[Mn(CO)3(η(6)-[2.2]paracyclophane)]PF6 | 222624-29-5

• 英文名称: [Mn(CO)3(η(6)-[2.2]paracyclophane)]PF6
• CAS: 222624-29-5
• 化学式: C₁₉H₁₆MnO₃*F₆P
• 分子量: 492.236
• InChiKey: DXAVLQWEEIWWPB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 五羰基溴化锰(I) 、 对二甲苯二聚体 在 catalyst: [1-Bu-3-Me-imidazolium]Cl-AlCl₃ 作用下， 以 melt 为溶剂， 以44%的产率得到[Mn(CO)3(η(6)-[2.2]paracyclophane)]PF6
  参考文献：
  名称：

  Chloroaluminate(III) ionic liquid mediated synthesis of transition metal–cyclophane; complexes: their role as solvent and Lewis acid catalyst

  摘要：

  The preparation of transition metal-cyclophane complexes using the ionic liquid system [bmim]Cl-AlCl3 ([bmim](+) = 1-butyl-3-methylimidazolium cation) as both the solvent and Lewis acid catalyst is described. Both known and novel complexes are prepared. Simple arene complexes of manganese have also been prepared in order to demonstrate the chemistry and these reactions are compared with the literature preparations conducted in conventional organic solvents. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00734-7