[(dippe)nickel(0)(η2-O,C-acetone)] | 1200115-17-8

• 英文名称: [(dippe)nickel(0)(η2-O,C-acetone)]
• CAS: 1200115-17-8
• 化学式: C₁₇H₃₈NiOP₂
• 分子量: 379.126
• InChiKey: UKHGCMJQBDEQTF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ((1,2-bis(diisopropylphosphino)ethane)NiH)2 、 丙酮 以 氘代甲苯 为溶剂， 以85%的产率得到[(dippe)nickel(0)(η2-O,C-acetone)]
  参考文献：
  名称：

  Selective hydrogenation of the CO bond of ketones using Ni(0) complexes with a chelating bisphosphine

  摘要：

  The nickel complexes [(dippe)Ni(eta(2)-O,C-benzophenone)] (2), [(dippe)Ni(eta(2)-O,C-4-methylbenzophenone)] (3), [(dippe)Ni(eta(2)-O,C-acetophenone)] (4), [(dippe)Ni(eta(2)-O,C-acetone)] (S), [(dippe)Ni(eta O-2,C-fluorenone)] (6), [(dippe)Ni(eta(2)-O,C-di(2-pyridyl) ketone)] (7a) [(dippe)Ni(kappa(2)-N,N-di(2-pyridyl) ketone)] (7b), [(dippe)Ni(kappa(2)-O,O-2,2'-pyridil)] (8), [(dippe)Ni(kappa(2)-O,O-benzil)] (9a), and [((dippe)Ni)(2)(eta(2)-O,C-benzil)] (9b) were prepared by the reaction of [(dippe)Ni(mu-H)](2) (1) with the corresponding ketone or 1,2-diketone at room temperature. The structures of compounds 2, 6, 9a and 9b were confirmed by X-ray crystallography. The selective hydrogenation of the two types of substrates was undertaken using H-2, giving high conversions to the corresponding reduction products, either alcohols or alkanes. Tunable reaction conditions to promote the partial or total hydrogenation (hydrogenolysis) of the substrates are described. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2009.05.026