[Pt((η5-C5H3-CHN-(CH2)3-N(CH3)2)Fe(η5-C5H5))Cl] | 597554-73-9

• 英文名称: [Pt((η5-C5H3-CHN-(CH2)3-N(CH3)2)Fe(η5-C5H5))Cl]
• CAS: 597554-73-9
• 化学式: C₁₆H₂₁ClFeN₂Pt
• 分子量: 527.736
• InChiKey: MMGPHLSVLGQZTC-UGSBBJTBSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dichlorobis(dimethyl sulfoxide)platinum(II) 、 [(η5-C5H5)Fe(η5-C5H4-CHN-(CH2)3-N(CH3)2)] 在 NaOOCCH₃ 作用下， 以 甲醇 、 甲苯 为溶剂， 生成 二茂铁甲醛 、 [Pt((η5-C5H3-CHN-(CH2)3-N(CH3)2)Fe(η5-C5H5))Cl] 、 cis-[PtCl2((η5-C5H5)Fe(η5-C5H4-CHN-(CH2)3-N(CH3)2))]
  参考文献：
  名称：

  The importance of the length of the –(CH2)n– chain on the cycloplatination of the [(η5-C5H5)Fe{(η5-C5H4)–CHN–(CH2)n–NMe2}] (n=2 or 3) ligands and the properties of the platinacycles

  摘要：

  The study of reaction of [(eta(5)-C5H5)Fe {(eta(5)-C5H4)-CH=N-(CH2)(2)-NMe2}] (1b) with cis-[PtCl2(dmso)(2)] under different experimental conditions is reported. When the reaction was carried out in the presence of NaOAc in 5 a OAc-/1b molar ratio = 2 in a mixture of toluene/methanol (20:5) under reflux for 3 days, the cycloplatinated complex: [Pt{[(eta(5)-C5H3)-CH=N-(CH2)(2)-NMe2]Fe(eta(5)-C5H5)}Cl(dmso)] (2b) together with small amounts of ferrocenecarboxaldehyde and cis-[Pt{(eta(5)-C5H5)Fe[(eta(5)-C5H4)CH=N-(CH2)(2)-NMe2])}Cl-2(dmso)] (3b) was isolated. The X-ray crystal structure of 2b confirmed that the ligand acts as a terdentate [C-(sp2,C-ferrocene),N,N'](-) group. Complex 2b reacted with the stoichiometric amount of PPh3 giving [Pt{[(eta(5)-C5H3)CH=N-(CH2)(2)-NMe2]Fe(eta(5)-C5H5)}Cl(PPh3)] (4b). Electrochemical studies of 2b-4b reveal that the proclivity of the ferrocenyl moiety to oxidise is dependent on the mode of binding of the ligand to the platinum(II). (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.04.004