| 258336-98-0

• CAS: 258336-98-0
• 化学式: C₁₅H₂₀BrN₄RuS*F₆P
• 分子量: 614.355
• InChiKey: VDFNYCMMETXHID-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 、 乙二胺 以 甲醇 、 水 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Synthesis, characterisation and reactivity of trans-[Ru(L)(PPh3)Br2]; L=2-pyridyl-N-(2′-methylthiophenyl)methyleneimine

  摘要：

  Reaction of Ru(PPh3)(2)Br-2 with the NNS chelating tridentate ligand 2-pyridyl-N-(2'-methylthiophenyl)methyleneimine (L) led to the isolation of the ruthenium(II) complex [Ru(L)(PPh3)Br-2]. Reactivity of this complex with different bidentate chelating ligands revealed that the products are quite different from those obtained by reacting Ru(L)(PPh3)Cl-2 (the corresponding cis dichloro complex) with the same ligands under comparable conditions. The mixed chelates were isolated and characterised by elemental analysis, magnetic moment measurement and by different spectroscopic methods along with their precursor. Electrochemistry of the complexes was examined by cyclic voltammetry using a platinum working electrode and a Ag/AgCl electrode as reference. The crystal structure of [Ru(L)(PPh3)Br-2] disclosed that, unlike Ru(L)(PPh3)Cl-2, the two bromo ligands are in trans position and this explained the difference in its reactivity pattern from the corresponding chloro complex. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00313-7