The preparation and properties of a new pentacyanomanganesenitric oxide anion, [Mn(CN)5NO]2−, and some observations on other pentacyanonitrosyl complexes
作者:F.A. Cotton、R.R. Monchamp、R.J.M. Henry、R.C. Young
DOI:10.1016/0022-1902(59)80183-4
日期:1959.4
The yellow anion [Mn(CN)5NO]2− may be prepared by oxidizing the purple [Mn(CN)5NO]3− with ∼6 N nitric acid in aqueous solution. Various salts may be isolated among which the silver, potassium and zinc salts have been prepared in pure form. The anion and its salts are only moderately stable. The silver and potassium salts are magnetically anomalous in the solid state; whereas the zinc salt in the solid