(4-pyridine carboxylic acid 2-butyne-1,4-diyl ester)Co2(CO)6 | 847043-00-9

• 英文名称: (4-pyridine carboxylic acid 2-butyne-1,4-diyl ester)Co2(CO)6
• 英文别名: (4-C5H4NCO2CHC)2Co2(CO)6
• CAS: 847043-00-9
• 化学式: C₂₂H₁₂Co₂N₂O₁₀
• 分子量: 582.331
• InChiKey: DAHRUGBRBLFZBA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (4-pyridine carboxylic acid 2-butyne-1,4-diyl ester)Co2(CO)6 、 [Pt(1,4-bis(diphenylphosphino)butane)(H2O)2][OTf]2 以 二氯甲烷 为溶剂， 以74%的产率得到[Pt(dppb)(4-C5H4NCO2CH2C)2Co2(CO)6][OTf]4
  参考文献：
  名称：

  Self‐Assembled Transition‐Metal Macrocycles and Two‐Dimensional Coordination Polymers Derived from Flexible C ₂ Co ₂ Cluster‐Bridged Bipyridine Ligands [(4‐C ₅ H ₄ NCO ₂ CH ₂ ) ₂ C ₂ Co ₂ (CO) ₆ ] and [(3‐C ₅ H ₄ NCO ₂ CH ₂ ) ₂ C ₂ Co ₂ (CO) ₆ ]

  摘要：

  AbstractReactions of the tetrahedral C2Co2 cluster‐bridged bipyridine ligand [(4‐C5H4NCO2CH2)2C2Co2(CO)6] (La) with [{M(dppb)(H2O)2}(OTf)2] (M = Pd, Pt; dppb = 1,4‐bis(diphenylphosphanyl)butane; OTf = SO3CF3) and AgX (X = NO3, SbF6) gave cationic metallamacrocycles [{M(dppb)La}2(OTf)4] (1, M = Pd; 2, M = Pt) and [(AgLa)2X2] (3, X = NO3; 4, X = SbF6). Furthermore, the isomeric C2Co2 cluster‐bridged bipyridine ligand [(3‐C5H4NCO2CH2)2C2Co2(CO)6] (Lb) reacted with ZnCl2 and AgX (X = PF6, ClO4) to afford cationic macrocycle [(ZnLbCl2)2] (5) and coordination polymers [(AgLbX)n] (6, X = PF6; 7, X = ClO4), respectively. Whereas flexible ligand La is known, Lb is new and could be prepared by reaction of but‐2‐yne‐1,4‐diyl dipyridine‐3‐carboxylate with [Co2(CO)8]. New self‐assembled products 1–7 and ligand Lb were characterized by elemental analysis and spectroscopy, and 1, 3–7, and Lb were additionally characterized by X‐ray crystallography. In addition, the electrochemistry of Lb and 5 were studied by cyclic voltammetry. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

  DOI：

  10.1002/ejic.200800953
• 作为产物：
  描述：

  dicobalt octacarbonyl 、 4-pyridinecarboxylic acid 2-butyne-1,4-diyl ester 以 petroleum ether 为溶剂， 以86%的产率得到(4-pyridine carboxylic acid 2-butyne-1,4-diyl ester)Co2(CO)6
  参考文献：
  名称：

  Cationic M(II)/Co(0) (M = Pd, Pt) Metallomacrocycles Containing Tetrahedral Co₂C₂ Cluster Cores Formed by Self-Assembly of Cluster-Bridged Bipyridine (4-C₅H₄NCO₂CH₂)₂C₂Co₂(CO)₆ and Diarsine-Chelated Complex [Pd(dpab)(H₂O)(OTf)][OTf] or [Pt(dpab)(H₂O)₂][OTf]₂

  摘要：

  The synthesis, characterization, and some reactions of the tetrahedral Co2C2 cluster-bridged bipyridine (4-C5H4NCO2CH2)(2)C2CO2(CO)(6) (2) and the diarsine-chelated complexes Pd(dpab)Cl-2 (3, dpab = 1,4-bis(diphenylarsino)butane), [Pd(dpab)(H2O)(OTf)][OTf] (4, OTf = SO3CF3) Pt(dpab)Cl-2 (5), and [Pt(dpab)(H2O)(2)] [OTf](2) (6) have been investigated. While the bridged bipyridine 2 could be prepared by reaction of 4-pyridinecarboxylic acid 2-butyne-1,4-diyl ester 1 with Co-2(CO)(8) in 86% yield, the chelated dichloride complexes 3 and 5 were obtained by reaction of K2PdCl4 or (PhCN)(2)PtCl2 with dpab in 90% and 77% yields. Further reactions of 3 and 5 with silver triflate followed by treatment with water afforded the corresponding chelated aqua/triflate complexes 4 and 6 in 92% and 88% yields. More interestingly, 4 and 6 were found to undergo self-assembly with 2 to give two cationic metallomacrocycles {[M(dpab)]-mu-[(4-C5H4NCO2CH2)(2)C2Co2(CO)(6)]}(2)[OTf](4) (7, M = Pd; 8, M = Pt) in 92% and 85% yields. X-ray crystal structures were determined for the Co2C2 cluster-containing metallomacroycles 7 and 8, as well as bipyridine 2 and complexes 4 and 6.

  DOI：

  10.1021/om049175y