(η3-C3H5)Pd(μ-SC6F5)P(C6H4OCH3-4)3 | 402723-46-0

• 英文名称: (η3-C3H5)Pd(μ-SC6F5)P(C6H4OCH3-4)3
• CAS: 402723-46-0
• 化学式: C₃₀H₂₇F₅O₃PPdS
• 分子量: 699.994
• InChiKey: BXWQOSHKCYUZAW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (η3-C3H5)Pd(μ-SC6F5)2Pd(η3-C3H5) 、 三(4-甲氧苯基)膦 以 丙酮 为溶剂， 以90%的产率得到(η3-C3H5)Pd(μ-SC6F5)P(C6H4OCH3-4)3
  参考文献：
  名称：

  Allyl–palladium compounds with fluorinated benzenethiolate ligands. X-ray crystal structure of [(η3-C3H5)Pd(μ-SC6H4F-4)2Pd(η3-C3H5)]

  摘要：

  Treatment of the di-lt-chloride allyl-palladium complex [(eta (3)-C3H5)Pd(mu -Cl)(2)Pd(eta (3)-C3H5)] with Pb(SR)(2) in acetone affords dinuclear fluorothiolate bridged complexes of the type [(eta (3)-C3H5)Pd(mu -SR)(2)Pd(eta (3)-C3H5)] (R = C6F5, 1; C6HF4-4, 2: C6H4F-2, 3; C6H4F-3, 4 and C6H4F-4, 5). Complex 1 reacts with pares-substituted phosphines P(C6H4X-4)(3) to give the mononuclear perfluorobenzenethiolate complexes [Pd(SC6F5)(eta (3)-C3H5)(P(C6H4X-4)(3))] (X = F, 6; CF3, 7; OCH3, 8 and CH3, 9). The single crystal X-ray diffraction structure of [(eta (3)-C3H5)Pd(mu -SC6H4F-4)(2)Pd(eta (3)-C3H5)] (5) has been resolved. (C) 2001 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(01)00934-2