HRh(CO)(p-CF3C6H4)3P)2(η2-C2H4) | 464875-74-9

• 英文名称: HRh(CO)(p-CF3C6H4)3P)2(η2-C2H4)
• CAS: 464875-74-9
• 化学式: C₄₅H₂₉F₁₈OP₂Rh
• 分子量: 1092.55
• InChiKey: SDRQDYFKUXHRFP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  乙烯 、 HRh(CO)(P(C6H4-4-CF3)3)3 以 二氧化碳 为溶剂， 生成 HRh(CO)(p-CF3C6H4)3P)2(η2-C2H4)
  参考文献：
  名称：

  Investigation of the hydroformylation of ethylene in liquid carbon dioxide

  摘要：

  In situ, high-pressure NMR was used to investigate the hydroformylation reaction of ethylene in liquid CO2 using Rh(CO)(2)acac as the catalyst precursor and (p-CF3C6H4)(3)P, tris(p-trifluoromethylphenyl)phosphine. as the ligand under different thermodynamic conditions (T= 10-23 degreesC P-CO = P-H2 = 10-15 bar. P-C3H4 = 10-15 bar. P-CO2 = 207 bar). H-1-NMR was used to monitor the reaction progress of the hydroformylation of ethylene with a rhodium catalyst under select conditions of temperature and CO2 solvent pressure. Potential resting states of the rhodium catalyst were investigated by P-31{H-1}-NMR. This is the first description of a rhodium catalyzed hydroformylation reaction in liquid CO2 monitored in situ by high pressure NMR. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01217-2