| 180794-49-4

• CAS: 180794-49-4
• 化学式: C₂₆H₃₄Cl₂Fe₂O₄P₂Pt
• 分子量: 850.181
• InChiKey: UEKOKAICBFEZMD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 (ferrocenylmethyl)bis(hydroxymethyl)phosphine 以 二氯甲烷 为溶剂， 以88%的产率得到
  参考文献：
  名称：

  Coordination complexes of the hydroxymethylphosphine FcCH2P(CH2OH)2 [Fc=(η5-C5H5)Fe(η5-C5H4)] and the X-ray crystal structure of the cationic gold bis(phosphine) complex [Au{FcCH2P(CH2OH)2}2]Cl

  摘要：

  Platinum(II) and palladium(II) complexes MCl2L2 and the gold(I) complex [AuL2]Cl of the air-stable ferrocene-derived hydroxymethylphosphine FcCH(2)P(CH2OH)(2) (L) have been synthesised by ligand substitution reactions, and the eta(6)-p-cymene ruthenium(II) complex RuCl2(eta(6)-C10H14)L has been synthesised by a chloride bridge-splitting reaction of the dimer [RuCl2(eta(6)-C10H14)](2). The cationic gold complex has been the subject of a single-crystal X-ray diffraction study, which shows the presence of the expected linearly coordinated bis(phosphine)gold cation, hydrogen-bonded to the chloride counterion and a lattice water molecule. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00211-3

文献信息

• FcCH₂P(CH₂OH)₂: a new, reactive yet air-stable ferrocene-derived phosphine [Fc =(η-C₅H₅)FeC₅H₄]
  作者：Nicholas J. Goodwin、William Henderson、J. Kwabena Sarfo

  DOI：10.1039/cc9960001551

  日期：——

  Reaction of FcCH(2)NMe(3)(+)I(-) with an excess of P(CH2OH)3 gives the air-stable ferrocenylphosphine FcCH(2)P(CH2OH)(2), characterised by an X-ray structure determination; reactivity towards reagents such as MeI, acrylonitrile and amines allows the synthesis of a range of new ferrocene-phosphine derivatives.