bis(diethylenetriamine)thallium(III) | 61037-37-4

• 英文名称: bis(diethylenetriamine)thallium(III)
• CAS: 61037-37-4
• 化学式: C₈H₂₆N₆Tl
• 分子量: 410.718
• InChiKey: ZRIKCCYTFFSRMN-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  thallium(III) perchlorate 、 二乙烯三胺 以 水 为溶剂， 生成 bis(diethylenetriamine)thallium(III)
  参考文献：
  名称：

  Novel bis(diethylenetriamine)thallium(III) complex. Synthesis and characterization in pyridine solution and in solid

  摘要：

  A new complex of thallium(ill) with the nitrogen donor ligand diethylenetriamine (dien) has been prepared and characterized by multinuclear NMR (H-1, C-13. Tl-205), infrared and Raman spectroscopy. and X-ray diffraction. In solution, the symmetric s-facial isomer of [Tl(dien)(2)](3+) is formed. This is a fluxional molecule even at low temperature (235 K): therefore, the different rotamers cannot be observed separately. A complete characterization of the complex is given from its non-trivial NMR spectra. The crystal structure of [Tl(dien)(2)](ClO4)(3).H2O shows u-facial geometry. where the coordination environment around thallium can be described as a distorted trigonal prism. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00813-1