[Pd(2-acetylthiophene thiosemicarbazone)Cl2] | 881736-88-5

• 英文名称: [Pd(2-acetylthiophene thiosemicarbazone)Cl2]
• CAS: 881736-88-5
• 化学式: C₇H₉Cl₂N₃PdS₂
• 分子量: 376.627
• InChiKey: OEFBZXSVXNQPPK-WNRDOTPUSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloro(cycloocta-1,5-diene)palladium (II) 、 1-(1-(thiophen-2-yl)ethylidene)thiosemicarbazide 以 乙醇 为溶剂， 以92%的产率得到[Pd(2-acetylthiophene thiosemicarbazone)Cl2]
  参考文献：
  名称：

  Platinum and palladium complexes of thiosemicarbazones derived of 2-acetylthiophene: Synthesis and spectral studies

  摘要：

  The reaction of 2-acetylthiophene thiosemicarbazone (2-HATT) and 2-acetylthiophene 4-phenylthiosemicarbazone (2-HAT-4-FT) with Pd(COD)Cl-2 (COD = 1,5-cyclooctadiene) and tranS-Pt2PEt3Cl4 yielded four new metal complexes: [Pd(2-HATT)Cl-2] (1), [Pd(2-ATT)(2)] (2), [Pd(2-AT-4-Fr)Cl] (3) and [Pt(2-ATT)(PEt3)Cl] (4). Apart from compound 3 all the others were characterised by H-1 and C-13{1H} NMR, infrared spectroscopy, and elemental analysis. Multinuclear NMR experiments of P-31{H-1} and Pt-195{H-1} of complex 4 have revealed that the ligand 2-HATT behaves as a bidentate chelating agent towards Pd(COD)Cl-2 and trans-Pt2PEt3Cl4 whereas ligand 2-HAT-4-Fr forms a tridentate chelating complex with Pd(COD)Cl-2. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2005.06.016