chlorotricarbonyl bis(4-trifluoromethylphenylimino)acenaphthene rhenium(I) | 873794-15-1

• 英文名称: chlorotricarbonyl bis(4-trifluoromethylphenylimino)acenaphthene rhenium(I)
• CAS: 873794-15-1
• 化学式: C₂₉H₁₄ClF₆N₂O₃Re
• 分子量: 774.092
• InChiKey: NQCCLRPBKFUEOV-WKRJOORVSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  五羰基氯铼(I) 、 N,N'-bis(4-(trifluoromethyl)phenyl)acenaphthene 以 甲苯 为溶剂， 以92%的产率得到chlorotricarbonyl bis(4-trifluoromethylphenylimino)acenaphthene rhenium(I)
  参考文献：
  名称：

  The use of sublimable chlorotricarbonyl bis(phenylimino)acenaphthene rhenium(I) complexes as photosensitizers in bulk-heterojunction photovoltaic devices

  摘要：

  A series of sublimable substituted chlorotricarbonyl bis(phenylimino) acenaphthene rhenium(I) complexes was synthesized and used in the fabrication of photovoltaic devices. The hole and electron carrier mobilities of these complexes are in the order of 10 (3) to 10 (4) cm(2) V (1) s (1). Heterojunction devices with CuPc/complex/C-60 (CuPc = copper phthalocyanine) as the active layer and bulk heterojunction devices with complex: C-60 as the active layer were fabricated. The rhenium complexes function as photosensitizer in the devices, and exhibit optical absorption in the region between 500 and 550 nm within which other components in the device do not absorb. Other devices with hole transport materials, exciton blocking materials, and different active layer thickness were also fabricated. Variation of substitution groups in the ligand did not show significant difference in device performance. The best power conversion efficiency of the devices was measured to be 1.29% under illumination of AM1.5 simulated solar light. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.04.037