| 1198587-23-3

• CAS: 1198587-23-3
• 化学式: C₄₀H₄₁Fe₄P
• 分子量: 776.127
• InChiKey: DFNNDHDFZPJBSP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  selenium 、 以 CH₂Cl₂ 为溶剂， 以98%的产率得到
  参考文献：
  名称：

  Redox-Active Phosphorus Ligands Bearing a [4Fe−4C] Core Substituent

  摘要：

  Reaction of [(eta(5)-C(5)H(4)Me)(4)Fe(4)(HCCH)(HCCBr)]-(PF(6)) (1) with HPPh(2) in the presence of NEt(3), followed by treatment of [Cp(2)Co], afforded [(eta(5)-C(5)H(4)Me)(4)Fe(4)(HCCH)-(HCC-PPh(2))] (2) The electron-rich [4Fe-4C] core substituent leads to the extremely electron-releasing character of the phosphine part, estimated by the J(PSe) coupling constant of the corresponding selenide [(eta(5)-C(5)H(4)Me)(4)Fe(4)(HCCH)(HCC-P(Se)Ph(2))] (3). Reaction of 2 with [AuCl(SMe(2))] gave [(eta(5)-C(5)H(4)Me)(4)Fe(4)(HCCH)(HCC-P(AuCl)Ph(2))] (4) The cyclic voltammogram of 4 shows two reversible one-electron oxidation waves, indicating the existence of one- and two-electron oxidized froms.

  DOI：

  10.1021/om900811u
• 作为产物：
  描述：

  在 cobaltocene 作用下， 以 acetonitrile 为溶剂， 以97%的产率得到
  参考文献：
  名称：

  Redox-Active Phosphorus Ligands Bearing a [4Fe−4C] Core Substituent

  摘要：

  Reaction of [(eta(5)-C(5)H(4)Me)(4)Fe(4)(HCCH)(HCCBr)]-(PF(6)) (1) with HPPh(2) in the presence of NEt(3), followed by treatment of [Cp(2)Co], afforded [(eta(5)-C(5)H(4)Me)(4)Fe(4)(HCCH)-(HCC-PPh(2))] (2) The electron-rich [4Fe-4C] core substituent leads to the extremely electron-releasing character of the phosphine part, estimated by the J(PSe) coupling constant of the corresponding selenide [(eta(5)-C(5)H(4)Me)(4)Fe(4)(HCCH)(HCC-P(Se)Ph(2))] (3). Reaction of 2 with [AuCl(SMe(2))] gave [(eta(5)-C(5)H(4)Me)(4)Fe(4)(HCCH)(HCC-P(AuCl)Ph(2))] (4) The cyclic voltammogram of 4 shows two reversible one-electron oxidation waves, indicating the existence of one- and two-electron oxidized froms.

  DOI：

  10.1021/om900811u