[(2,6-i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-2,6-(i-Pr2))AlMe2] | 686733-92-6

• 英文名称: [(2,6-i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-2,6-(i-Pr2))AlMe2]
• CAS: 686733-92-6
• 化学式: C₄₁H₅₄AlN₂P
• 分子量: 632.848
• InChiKey: VROBPUINIRHKHV-CUWITMTGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(2,6-i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-2,6-(i-Pr2))AlMe2] 、 三(五氟苯基)硼烷 以 further solvent(s) 为溶剂， 以99%的产率得到[(2,6-i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-2,6-(i-Pr2))AlMe][B(C6F5)3Me]
  参考文献：
  名称：

  Neutral and Cationic Group 13 Alkyl and Hydride Complexes of a Phosphinimine−Amide Ligand

  摘要：

  The phosphinimine-amine ligand 1 reacts with MR3 (M = Al, Ga; R = Me, H) with loss of RH to form the complexes (i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-i-Pr-2)MMe2 (M = Al (2), Ga (3)) and (i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-i-Pr-2)AlH2 (4). Subsequent reactions of 2 and 3 with [Ph3C] [B(C6F5)(4)] afforded [(i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-i-Pr-2)MMe] [B(C6F5)(4)] (M = Al (5), Ga (6)), while similar reactions of 2 and 3 with B(C6F5)(3) gave [(i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-i-Pr-2)MMe] [B(C6F5)(3)Mel (M = Al (8), Ga (9)). The analogous reactions of 4 with [Ph3C] [B(C6F5)(4)] and B(C6F5)(3) resulted in the formation of [(i-Pr2C6H3N)C(Me)CHPPh2-(NC6H3-i-Pr(2)AIH] [B(C6F5)(4)] (10) and [(i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-i-Pr-2)AIH] [B(C6F5)(3)H]- (11), respectively. Crystallographic studies of 1, 2, 4, and [(i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-i-Pr(2))AIMe(OEt2)] [B(C6F5)(4)] (7) are reported.

  DOI：

  10.1021/om0306776
• 作为产物：
  描述：

  三甲基铝 、 (2,6-i-Pr2C6H3NH)C(Me)CHPPh2(NC6H3-2,6-(i-Pr2)) 以 正戊烷 为溶剂， 以60%的产率得到[(2,6-i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-2,6-(i-Pr2))AlMe2]
  参考文献：
  名称：

  Neutral and Cationic Group 13 Alkyl and Hydride Complexes of a Phosphinimine−Amide Ligand

  摘要：

  The phosphinimine-amine ligand 1 reacts with MR3 (M = Al, Ga; R = Me, H) with loss of RH to form the complexes (i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-i-Pr-2)MMe2 (M = Al (2), Ga (3)) and (i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-i-Pr-2)AlH2 (4). Subsequent reactions of 2 and 3 with [Ph3C] [B(C6F5)(4)] afforded [(i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-i-Pr-2)MMe] [B(C6F5)(4)] (M = Al (5), Ga (6)), while similar reactions of 2 and 3 with B(C6F5)(3) gave [(i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-i-Pr-2)MMe] [B(C6F5)(3)Mel (M = Al (8), Ga (9)). The analogous reactions of 4 with [Ph3C] [B(C6F5)(4)] and B(C6F5)(3) resulted in the formation of [(i-Pr2C6H3N)C(Me)CHPPh2-(NC6H3-i-Pr(2)AIH] [B(C6F5)(4)] (10) and [(i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-i-Pr-2)AIH] [B(C6F5)(3)H]- (11), respectively. Crystallographic studies of 1, 2, 4, and [(i-Pr2C6H3N)C(Me)CHPPh2(NC6H3-i-Pr(2))AIMe(OEt2)] [B(C6F5)(4)] (7) are reported.

  DOI：

  10.1021/om0306776