| 157172-25-3

• CAS: 157172-25-3
• 化学式: C₂₃H₃₂Fe₂O₆P₂
• 分子量: 578.145
• InChiKey: MDGVQHNBHYBHND-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二茂铁乙炔 、 在 MeLi 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 以74%的产率得到
  参考文献：
  名称：

  Oxidized FeII ferrocenylacetylide complexes. A novel type of mixed-valence complex

  摘要：

  Reaction of lithium ferrocenylacetylide with (eta-C5H5)LL'FeI (L = L' = CO, L = L' = P(OMe)3, and L = CO, L' = PPh3) gave the corresponding Fe(II) ferrocenylacetylide complexes, (eta-C5H5)LL'FeCCFc, in moderate yields. (Eta-C5Me5)(CO)2FeCCFc was similarly prepared. In their cyclic voltammograms, all the complexes gave two irreversible waves in acetonitrile. The complexes, when oxidized with various oxidants, showed a broad absorption in the near-infrared region and low frequency-shift of the acetylide group in the IR spectrum. The spectral data suggest that the oxidized complexes are a novel Class II type of mixed-valence complex.

  DOI：

  10.1016/0022-328x(94)88123-5