[Pd([(MeO2CC=CCO2Me)(η5-C5H3)CH=N(C6H4-2-CH2OH)]Fe(η5-C5H5)Cl] | 877996-97-9

• 英文名称: [Pd([(MeO2CC=CCO2Me)(η5-C5H3)CH=N(C6H4-2-CH2OH)]Fe(η5-C5H5)Cl]
• CAS: 877996-97-9
• 化学式: C₂₄H₂₂ClFeNO₅Pd
• 分子量: 602.162
• InChiKey: NQGDIPJNVHIULQ-UMWSPTCWSA-M

反应信息

• 作为产物：
  描述：

  [Pd([(η5-C5H3)CH=N(C6H4-2-CH2OH)]Fe(η5-C5H5))Cl] 、 丁炔二酸二甲酯 以 二氯甲烷 为溶剂， 生成 [Pd([(MeO2CC=CCO2Me)(η5-C5H3)CH=N(C6H4-2-CH2OH)]Fe(η5-C5H5)Cl] 、 [Pd([(MeO2CC=CCO2Me)2(η5-C5H3)CH=N(C6H4-2-CH2OH)]Fe(η5-C5H5)Cl]
  参考文献：
  名称：

  Novel Palladacycles Containing [C(sp², ferrocene), N, O]^- or [C(sp², ferrocene), N, O]^2- Terdentate Ligands

  摘要：

  The synthesis, characterization, and study of the reactivity of the novel cyclopalladated complexes [Pd{[(eta(5)-C5H3)CH=N(C6H4-2-CH2OH)]Fe(eta(5)-C5H5)}CI] (2) and [Pd{[(eta(5)-C5H3)CH N(C6H4-2-CH2O)]-Fe(eta(5)-C5H5)}](2) (3) With PPh3 or MeO2CC CCO2Me are described. Electrochemical and Fe-57 Mossbauer spectroscopic studies of the new palladacycles are also reported.

  DOI：

  10.1021/om050881o