sym-mer-tricarbonyl-pyridine-bis(1,4-dimethyl-1,2,3,4-tetrazolin-5-ylidene)chromium(0) | 899833-25-1

• 英文名称: sym-mer-tricarbonyl-pyridine-bis(1,4-dimethyl-1,2,3,4-tetrazolin-5-ylidene)chromium(0)
• CAS: 899833-25-1
• 化学式: C₁₄H₁₇CrN₉O₃
• 分子量: 411.343
• InChiKey: OMLXHAYGVRODHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  sym-mer-tricarbonyl-pyridine-bis(1,4-dimethyl-1,2,3,4-tetrazolin-5-ylidene)chromium(0) 、 1-异苯甲腈 以 四氢呋喃 为溶剂， 以57%的产率得到sym-mer-tricarbonyl-phenylisocyanid-bis(1,4-dimethyl-1,2,3,4-tetrazolin-5-ylidene)chromium(0)
  参考文献：
  名称：

  Tetrazole and triazole carbene complexes of group 6 metal carbonyls

  摘要：

  In order to study the relative stability of cis- and trans-isomers of bis(NHC)tetracarbonyl complexes of group 6 metals, we synthesized the corresponding complexes with triazolin- and tetrazolinylidene ligands. By reaction of the free carbene (L = 1,3,4-triphenyl-4,5-dihydro-1H-1,2,4-triazolin-5-ylidene)-first synthesized by Enders - with the hexacarbonyls of Cr, Mo and W the corresponding M(L)(CO)(5) complexes are generated. Depending on an excess of carbene also the cis-(L)(2)Mo(CO)(4) complex was obtained. The latter can be photolytically converted to the trans-(L)(2)Mo(CO)(4) complex. The corresponding complexes with the 1,4-dimethyltetrazolin-5-ylidene ligand (L'), Cr(L')(CO)(5), cis-(L')(2)Cr(CO)(4) and trans-(L')(2)Cr(CO)(4) can be obtained by reaction of hexacarbonyl-mu-trihydroxy-dichromate with dimethyltetrazolium salt. In the cis-(L')(2)Cr(CO)(4) complex, one carbonyl ligand can be replaced by donor ligands such as pyridine or phenylisocyanide to form sym-mer-tricarbonyl complexes. All new complexes are fully characterized by spectroscopy and most by single-crystal X-ray analysis. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.09.049
• 作为产物：
  描述：

  吡啶 、 tetracarbonyl-cis-[bis(1,4-dimethyl-1,2,3,4-tetrazolin-5-ylidene)]chromium(0) 以 乙醚 为溶剂， 以53%的产率得到sym-mer-tricarbonyl-pyridine-bis(1,4-dimethyl-1,2,3,4-tetrazolin-5-ylidene)chromium(0)
  参考文献：
  名称：

  Tetrazole and triazole carbene complexes of group 6 metal carbonyls

  摘要：

  In order to study the relative stability of cis- and trans-isomers of bis(NHC)tetracarbonyl complexes of group 6 metals, we synthesized the corresponding complexes with triazolin- and tetrazolinylidene ligands. By reaction of the free carbene (L = 1,3,4-triphenyl-4,5-dihydro-1H-1,2,4-triazolin-5-ylidene)-first synthesized by Enders - with the hexacarbonyls of Cr, Mo and W the corresponding M(L)(CO)(5) complexes are generated. Depending on an excess of carbene also the cis-(L)(2)Mo(CO)(4) complex was obtained. The latter can be photolytically converted to the trans-(L)(2)Mo(CO)(4) complex. The corresponding complexes with the 1,4-dimethyltetrazolin-5-ylidene ligand (L'), Cr(L')(CO)(5), cis-(L')(2)Cr(CO)(4) and trans-(L')(2)Cr(CO)(4) can be obtained by reaction of hexacarbonyl-mu-trihydroxy-dichromate with dimethyltetrazolium salt. In the cis-(L')(2)Cr(CO)(4) complex, one carbonyl ligand can be replaced by donor ligands such as pyridine or phenylisocyanide to form sym-mer-tricarbonyl complexes. All new complexes are fully characterized by spectroscopy and most by single-crystal X-ray analysis. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.09.049