[Mn2(CO)6(μ-H)(μ-(triisopropylphosphino)ethenetrithiolate)] | 561299-48-7

• 英文名称: [Mn2(CO)6(μ-H)(μ-(triisopropylphosphino)ethenetrithiolate)]
• 英文别名: Mn2(CO)6(μ-H)(μ-S(SC3H5)CC(P(i-Pr)3)S]
• CAS: 561299-48-7
• 化学式: C₂₀H₂₇Mn₂O₆PS₃
• 分子量: 600.479
• InChiKey: ZAKRKVYIGJMPPW-XEYCFEOVSA-M

反应信息

• 作为产物：
  描述：

  Li[Mn2(CO)6(μ-H)(μS3CCP(i-Pr)3)] 、 3-溴丙烯 以 四氢呋喃 为溶剂， 以55%的产率得到[Mn2(CO)6(μ-H)(μ-(triisopropylphosphino)ethenetrithiolate)]
  参考文献：
  名称：

  A homodinuclear complex of manganese containing novel ligand, Mn2(CO)6(μ-H){μ-S(SC3H5)CC(PPr3i)S}

  摘要：

  The title complex Mn-2(CO)(6)(mu-H){mu-S(SC3H5)C=C(PPr3i)S} was synthesized by allyation of the homobinuclear anion [Mn-2(CO)(6)(mu-H){mu-S(SC3H5)C=C(PPr3i)S}](-1), and characterized by elemental analysis, IR, H-1 NMR and P-31 NMR spectra. The molecular structure shows that it contains a novel fairly planar ligand S(S)C=C(PPr3i)S, and the two Mn(CO)(3) fragments 3 are symmetrically placed at both sides of the plane of the ligand. (C) 2003 Published by Elsevier Science B.V.

  DOI：

  10.1016/s0022-2860(03)00022-x