chlorido(η6-p-cymene)(imidzole)(triphenylphosphine)ruthenium(II) hexafluorophosphate | 1357080-73-9

• 英文名称: chlorido(η6-p-cymene)(imidzole)(triphenylphosphine)ruthenium(II) hexafluorophosphate
• CAS: 1357080-73-9
• 化学式: C₃₁H₃₃ClN₂PRu*F₆P
• 分子量: 746.077
• InChiKey: VXRVAQIYKFEAKW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  咪唑 、 [RuII(η6-p-cymene)(PPh3)(CH3CN)Cl]PF6 以 二氯甲烷 为溶剂， 以99%的产率得到chlorido(η6-p-cymene)(imidzole)(triphenylphosphine)ruthenium(II) hexafluorophosphate
  参考文献：
  名称：

  Synthesis of [RuII(η6-p-cymene)(PPh3)(L)Cl]PF6 complexes with carbohydrate-derived phosphites, imidazole or indazole co-ligands

  摘要：

  Ru-II(arene) complexes of the general formula [Ru-II(eta(6)-p-cymene)(PPh3)(L)Cl]PF6 with L = P- or N-donor systems have been synthesized and characterized. Carbohydrate-derived phosphites, imidazole or indazole have been chosen as co-ligands and different synthetic routes have been explored to obtain the compounds. The organometallics were characterized by elemental analysis, electrospray ionization mass spectroscopy, H-1, C-13{H-1}, P-31{H-1} and 2D NMR spectroscopic methods. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.10.007