1,2-diferrocenyl-4,5-dimethylbenzene | 1374017-39-6

• 英文名称: 1,2-diferrocenyl-4,5-dimethylbenzene
• CAS: 1374017-39-6
• 化学式: C₂₈H₂₆Fe₂
• 分子量: 474.208
• InChiKey: DGYUXUKZQKQFRZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二茂铁乙炔 、 (2-butyne)hexacarbonyldicobalt 以 1,4-二氧六环 为溶剂， 以63%的产率得到1,2-diferrocenyl-4,5-dimethylbenzene
  参考文献：
  名称：

  Synthesis of ortho-diferrocenylbenzene with cobalt clusters as reaction precursors: Crystal structure and electrochemical properties

  摘要：

  Five new ortho-diferrocenylbenzene derivatives, 1,2-diferrocenyl-4,5-dimethylbenzene (2), 1,2-diferrocenyl-4,5-diphenylbenzene (3), 1,2-diferrocenyl-4,5-ditrimethylsilylbenzene (4), 1,2-diferrocenyl-3,4,5,6-tetramethylbenzene(5), and 1,2-diferrocenyl-3,4,5,6-tetraphenyl -benzene (6), were synthesized through the cycloaddition reactions of alkynes with the cobalt cluster Co-2(CO)(6)(mu(2)-alkyne) as reaction precursors, and characterized by elemental analysis, FT-IR, NMR, and MS. The molecular structures of compounds (2-6) were identified using single-crystal X-ray diffraction, and the electron interactions between two ferrocenyl units of each of the five compounds were investigated using cyclic voltammetric techniques. The results of electrochemical experiment indicated that the charge density of the aryl bridge is the key factor that influences electron communications between two ferrocenyl units. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.02.018