{Rh(I)(tetrafluorobenzobicyclo-{2.2.2}octadiene)(3,5-bis(pyridin-2-yl)-1,2,4-triazole)}{RhCl2(tetrafluorobenzobicyclo-{2.2.2}octadiene)} | 141876-26-8

• 英文名称: {Rh(I)(tetrafluorobenzobicyclo-{2.2.2}octadiene)(3,5-bis(pyridin-2-yl)-1,2,4-triazole)}{RhCl2(tetrafluorobenzobicyclo-{2.2.2}octadiene)}
• CAS: 141876-26-8
• 化学式: C₁₂H₆Cl₂F₄Rh*C₂₄H₁₅F₄N₅Rh
• 分子量: 952.3
• InChiKey: AJUNNAMMGNRGDD-CGKXDFJKSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {Rh(I)(tetrafluorobenzobicyclo-{2.2.2}octadiene)(3,5-bis(pyridin-2-yl)-1,2,4-triazole)}{RhCl2(tetrafluorobenzobicyclo-{2.2.2}octadiene)} 在 CO 作用下， 以 二氯甲烷 为溶剂， 生成 {Rh(I)(CO)2(3,5-bis(pyridin-2-yl)-1,2,4-triazole)}{RhCl2(CO)2}
  参考文献：
  名称：

  Mono- and dinuclear rhodium(I) complexes containing the ligand 3,5-bis(pyridin-2-yl)-1,2,4-triazole

  摘要：

  Reactions of [RhClL2] (L2 = diolefin or (CO)(PPh3)) with the deprotonated form of the ligand 3,5-bis(pyridin-2-yl)-1,2,4-triazole (Hbpt) gave neutral, mononuclear complexes [Rh(L2)(bpt)]. Cationic, mono- and dinuclear species of formulae [Rh(L2)(Hbpt)]+, [{RhL2}2(bpt)+ and [{RhL2}2(Hbpt)]2+, where L2 = diolefin, (CO)2 or (CO)(PPh3), have also been prepared. Ion-pair complexes of formulae [Rh(L2)(Hbpt)][RhCl2L2] were obtained by adding Hbpt to dichloromethane solutions of [RhClL2]2.

  DOI：

  10.1016/s0020-1693(00)93464-9
• 作为产物：
  描述：

  [Rh2(μ-Cl)2(tetrafluorobenzobarrelene)2] 、 3,5-di(pyridin-2-yl)-1,2,4-triazole 以 二氯甲烷 为溶剂， 以72%的产率得到{Rh(I)(tetrafluorobenzobicyclo-{2.2.2}octadiene)(3,5-bis(pyridin-2-yl)-1,2,4-triazole)}{RhCl2(tetrafluorobenzobicyclo-{2.2.2}octadiene)}
  参考文献：
  名称：

  Mono- and dinuclear rhodium(I) complexes containing the ligand 3,5-bis(pyridin-2-yl)-1,2,4-triazole

  摘要：

  Reactions of [RhClL2] (L2 = diolefin or (CO)(PPh3)) with the deprotonated form of the ligand 3,5-bis(pyridin-2-yl)-1,2,4-triazole (Hbpt) gave neutral, mononuclear complexes [Rh(L2)(bpt)]. Cationic, mono- and dinuclear species of formulae [Rh(L2)(Hbpt)]+, [{RhL2}2(bpt)+ and [{RhL2}2(Hbpt)]2+, where L2 = diolefin, (CO)2 or (CO)(PPh3), have also been prepared. Ion-pair complexes of formulae [Rh(L2)(Hbpt)][RhCl2L2] were obtained by adding Hbpt to dichloromethane solutions of [RhClL2]2.

  DOI：

  10.1016/s0020-1693(00)93464-9