| 633323-25-8

• CAS: 633323-25-8
• 化学式: C₃₀H₄₅N₂U
• 分子量: 671.73
• InChiKey: YBTHEJYOSRCATP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 氘代苯 为溶剂， 生成 tris(pentamethylcyclopentadienyl)uranium(III)
  参考文献：
  名称：

  A Monometallic f Element Complex of Dinitrogen:  (C₅Me₅)₃U(η-N₂)

  摘要：

  The reactivities of (C5Me5)3U and (C5Me4H)3U were compared using both common (THF) and nontraditional (N2) ligands for f elements. THF coordinates the less-crowded (C5Me4H)3U to form (C5Me4H)3U(THF) while ring opening occurs with sterically crowded (C5Me5)3U. N2 at 80 psi reacts with (C5Me5)3U to form (C5Me5)3U(eta1-N2) [U-N(N2) = 2.492(10) A, nu(N2) = 2207 cm-1, and cnt-U-N2 = 90 degrees ], whereas only (C5Me4H)3U was isolated under 80 psi of N2.

  DOI：

  10.1021/ja037647e
• 作为产物：
  描述：

  tris(pentamethylcyclopentadienyl)uranium(III) 、 氮 以 not given 为溶剂， 生成
  参考文献：
  名称：

  A Monometallic f Element Complex of Dinitrogen:  (C₅Me₅)₃U(η-N₂)

  摘要：

  The reactivities of (C5Me5)3U and (C5Me4H)3U were compared using both common (THF) and nontraditional (N2) ligands for f elements. THF coordinates the less-crowded (C5Me4H)3U to form (C5Me4H)3U(THF) while ring opening occurs with sterically crowded (C5Me5)3U. N2 at 80 psi reacts with (C5Me5)3U to form (C5Me5)3U(eta1-N2) [U-N(N2) = 2.492(10) A, nu(N2) = 2207 cm-1, and cnt-U-N2 = 90 degrees ], whereas only (C5Me4H)3U was isolated under 80 psi of N2.

  DOI：

  10.1021/ja037647e