[((13)CO)Pt(μ-P(C(CH3)3)2)2Pt(hydride)(PH(C(CH3)3)2)](SO3CF3) | 443095-08-7

• 英文名称: [((13)CO)Pt(μ-P(C(CH3)3)2)2Pt(hydride)(PH(C(CH3)3)2)](SO3CF3)
• CAS: 443095-08-7
• 化学式: CF₃O₃S*C₂₅H₅₆OP₃Pt₂
• 分子量: 1005.86
• InChiKey: DZWRSCIWJGTMPJ-YCVRGHOZSA-M

反应信息

• 作为反应物：
  描述：

  [((13)CO)Pt(μ-P(C(CH3)3)2)2Pt(hydride)(PH(C(CH3)3)2)](SO3CF3) 、 苯乙炔 以 丙酮 为溶剂， 生成 [((13)CO)(PH(C(CH3)3)2)Pt(μ-P(C(CH3)3)2)(μ-hydride)Pt(η1-CCC6H5)(PH(C(CH3)3)2)](SO3CF3)
  参考文献：
  名称：

  Stable η¹-Alkynyl−μ,η¹:η²-Alkenyl Complexes from the Reaction of Terminal Alkynes with Encumbered Dinuclear Platinum Compounds and Their Formyl, Methoxycarbonyl, and Hydride Derivatives

  摘要：

  The stepwise reaction of terminal alkynes with [(OC)Pt(mu-PBu2t)(2)Pt(H)((PBu2H)-H-t)]OTf yields intermediate eta(1)-alkynyl -hydride-bridged complexes, and then stable eta(1)-alkynyl/alkenyl-bridged derivatives containing an electrophilic carbonyl ligand. The latter is attacked by nucleophiles (H- and MeO-) to give a rare platinum formyl species, which is slowly converted into a stable hydride or a stable methoxycarbanyl complex.

  DOI：

  10.1021/om020133o