[2,5-(diphenyl-κC(2'),κC(2''))]-1,3,4-oxadiazole-(κN1,κN2)bis(tetracarbonylmanganese(I)) | 930297-47-5

• 英文名称: [2,5-(diphenyl-κC(2'),κC(2''))]-1,3,4-oxadiazole-(κN1,κN2)bis(tetracarbonylmanganese(I))
• CAS: 930297-47-5
• 化学式: C₂₂H₈Mn₂N₂O₉
• 分子量: 554.19
• InChiKey: USQAIVLWBLJMJG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  benzylpentacarbonylmanganese 、 2,5-二苯基-1,3,4-恶二唑 以 正庚烷 为溶剂， 以75%的产率得到[2,5-(phenyl-κC(2''),phenyl)]-1,3,4-oxadiazole-(κN1)(tetracarbonylmanganese(I))
  参考文献：
  名称：

  Synthesis of cyclomanganated complexes derived from 2,5-diphenyl-1,3,4-oxadiazole and their reactivity with respect to 1,1-diphenyldiazomethane: Evidence for a fluxional trihaptobenzylic coordination mode

  摘要：

  The cyclornetallation of 2,5-diphenyl-1,3,4-oxadiazole with benzylpentacarbonylmanganese afforded the related mono- and binuclear complexes. The thermolytic coupling of 1,1-diphenyldiazomethane with monometallated 2,5-diphenyl-1,3,4-oxadiazole afforded substantial amounts of a new trihaptobenzylic complex. In the solid state, an X-ray diffraction analysis confirmed the coordination of manganese metal to one of the phenyl groups introduced by the 1,1-diphenyidiazomethane and to one of ligand's nitrogen centre. In solution, this trihaptobenzylic complex displays a fluxionality which is assumed to be related to the equilibration of its helical Lambda and Delta enantiomers. @ 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.11.007