作者:John R. Chipperfield、Stephen Clark、David E. Webster、Halimahton Yusof
DOI:10.1016/0022-328x(91)86405-f
日期:1991.12
Rate coefficients are reported for the cleavage by halogens of tintransition-metal bonds in compoundscontaining two or more such bonds. Bond reactivity with iodine is in the order SnCo ≈ Sn-Fe > Sn-Mo ≈ Sn-W > Sn-Mn. Rates of halogenation of compoundscontaining three tintransition-metal bonds show that a subtle balance between steric and electronic effects determines bond reactivity.