cymantrenylferrocene | 37048-11-6

• 英文名称: cymantrenylferrocene
• CAS: 37048-11-6
• 化学式: C₁₈H₁₃FeMnO₃
• 分子量: 388.084
• InChiKey: FJXZZTFHKUPRND-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  五羰基溴化锰(I) 、 以 苯 为溶剂， 以52%的产率得到cymantrenylferrocene
  参考文献：
  名称：

  Synthesis of Fulvalene-Bridged Bimetallic Compounds Containing a Substituted Cyclopentadienyl Group Based on Pauson−Khand Chemistry

  摘要：

  From the Pauson-Khand products 2-ferrocenylcyclopentenone (2) and 2-ferrocenyl-3-methylcyclopentenone (10) as starting materials, substituted ferrocene complexes (C5H5-eta(5)-C5H4)Fe(C5H5) (4), (CH3C5H4-eta(5)-C5H4)Fe(C5H5) (12), and (Me2C5H3-eta(5)-C5H4)Fe(C5H5) (16) were prepared. Metalation of 4, 12, and 16 with Mn(CO)(5)Br, Cr(CO)(3)(CH3CN)(3), FeCl2(THF)(n), and the deprotonated form of [CpFe(fluorene)](+) resulted in good yields of fulvalenyl-bridged heterobi- and polymetallic compounds. The molecular structures of [1-{(C5H4)Fe(C5H5)}-2-CH3C5H4]Mn(CO)(3) (13), [2-{(C5H4)Fe(C5H5)}-1,3-Me2C5H2] Mn(CO)(3) (17), [2-{(C5H4)Fe(C5H5)}-1,3-Me2C5H2]Fe(C5H5) (18), and [1-{(C5H4)Fe(C5H5)}-2,3,4,5-Me4C5]Fe(C5H5) (23) are reported.

  DOI：

  10.1021/om980693g