| 165751-19-9

• CAS: 165751-19-9
• 化学式: C₂₅H₁₄MnMoO₈P
• 分子量: 624.233
• InChiKey: LHHCERLJXDBVMG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 碘 以 not given 为溶剂， 以100%的产率得到[(η5-C5H4PPh2)Mo(CO)3I]
  参考文献：
  名称：

  Formation of Mo-Pd and W-Pd Complexes. Insight into the Mechanism of Palladium-Catalyzed Metal-Carbon Bond Formation

  摘要：

  The oxidative addition of M-I moieties M-I moieties (M = Mo, W) at Pd-O was investigated in order to elucidate the mechanism of palladium-catalyzed metal-carbon bond formation. By the use of metal phosphine-substituted cyclopentadienyl iodo complexes of formula [eta(5)-(Ph(2)P)C5H4](CO)(3)MI (M = Mo, W) it was possible to isolate and characterize a product of oxidative addition to zerovalent palladium, [eta(5)-(Ph(2)P)C5H4](CO)(3)MPd-(PPh(3))I (M = Mo, W).

  DOI：

  10.1021/om00007a011
• 作为产物：
  描述：

  五羰基溴化锰(I) 、 Li(1+)*[(η5-C5H4PPh2)Mo(CO)3](1-) 以 not given 为溶剂， 以46%的产率得到
  参考文献：
  名称：

  Formation of Mo-Pd and W-Pd Complexes. Insight into the Mechanism of Palladium-Catalyzed Metal-Carbon Bond Formation

  摘要：

  The oxidative addition of M-I moieties M-I moieties (M = Mo, W) at Pd-O was investigated in order to elucidate the mechanism of palladium-catalyzed metal-carbon bond formation. By the use of metal phosphine-substituted cyclopentadienyl iodo complexes of formula [eta(5)-(Ph(2)P)C5H4](CO)(3)MI (M = Mo, W) it was possible to isolate and characterize a product of oxidative addition to zerovalent palladium, [eta(5)-(Ph(2)P)C5H4](CO)(3)MPd-(PPh(3))I (M = Mo, W).

  DOI：

  10.1021/om00007a011