[Au(III)Cl2(2-(2-thiazolyl)phenyl)] | 364751-02-0

• 英文名称: [Au(III)Cl2(2-(2-thiazolyl)phenyl)]
• CAS: 364751-02-0
• 化学式: C₉H₆AuCl₂NS
• 分子量: 428.092
• InChiKey: CPSAHQHZBPRANW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Au(III)Cl2(2-(2-thiazolyl)phenyl)] 以 二氯甲烷 、 丙酮 为溶剂， 生成 [Au(III)Cl(2-(2-thiazolyl)phenyl)(PPh3)2]BF4
  参考文献：
  名称：

  Synthesis and reactivity of the five-membered cycloaurated complexes of 2-phenylthiazole

  摘要：

  2-Phenylthiazole (Hphtz) reacted with H[AuCl4]. 4H(2)O to give the salt [H(Hphtz)][AuCl4] (1), while the reaction of Hphtz with Na[AuCl4]. 2H(2)O or AuCl3. 4H(2)O afforded the adduct [AuCl3(Hphtz-N)] (2). When the adduct 2 was heated in 1,2-dichloroethane in the presence of AgBF4, cycloauration took place to produce [AuCl2(phtz-C-1, N)] [phtz = 2-(2-thiazolyl)phenyl] (3). The reactivity of 3 towards Tl(acac) and PPh3 was investigated. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00432-7
• 作为产物：
  描述：

  2-苯基噻唑 在 AgBF₄ 作用下， 以 二氯甲烷 、 水 、 乙腈 为溶剂， 生成 [Au(III)Cl2(2-(2-thiazolyl)phenyl)]
  参考文献：
  名称：

  Synthesis and reactivity of the five-membered cycloaurated complexes of 2-phenylthiazole

  摘要：

  2-Phenylthiazole (Hphtz) reacted with H[AuCl4]. 4H(2)O to give the salt [H(Hphtz)][AuCl4] (1), while the reaction of Hphtz with Na[AuCl4]. 2H(2)O or AuCl3. 4H(2)O afforded the adduct [AuCl3(Hphtz-N)] (2). When the adduct 2 was heated in 1,2-dichloroethane in the presence of AgBF4, cycloauration took place to produce [AuCl2(phtz-C-1, N)] [phtz = 2-(2-thiazolyl)phenyl] (3). The reactivity of 3 towards Tl(acac) and PPh3 was investigated. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00432-7

文献信息

• Synthesis of Cyclometalated Gold(III) Complexes via Catalytic Rhodium to Gold(III) Transmetalation
  作者：Jaime Martín、Enrique Gómez‐Bengoa、Alexandre Genoux、Cristina Nevado

  DOI：10.1002/anie.202116755

  日期：2022.5.9

  A catalytic method for the straightforward synthesis of cyclometalated (C^N)gold(III) complexes is reported via an unprecedented, redox-neutral Rh-to-AuIII transmetalation. A rate-determining transfer of the C ligand followed by the subsequent incorporation of the N donor delivers the monocyclometalated (C^N) gold(III) species.

  报道了一种直接合成环金属化 (C^N)gold(III) 配合物的催化方法，该方法是通过前所未有的、氧化还原中性的 Rh-to-Au III转金属化反应实现的。C 配体的速率决定转移，然后是 N 供体的随后掺入，提供单环金属化 (C^N) 金 (III) 物质。