[(n-BuSn(2-pyridyl)3)W(CO)3] | 375842-81-2

• 英文名称: [(n-BuSn(2-pyridyl)3)W(CO)3]
• CAS: 375842-81-2
• 化学式: C₂₂H₂₁N₃O₃SnW
• 分子量: 677.987
• InChiKey: PWWFIGYTHGQGQV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-溴吡啶 在 n-BuLi 作用下， 以 四氢呋喃 为溶剂， 生成 [(n-BuSn(2-pyridyl)3)W(CO)3]
  参考文献：
  名称：

  Molybdenum and Tungsten Tricarbonyl Complexes with the Tripodal Ligands [ⁿBuSn(2-pyridyl)₃] and [RSn(methylthiomethyl)₃]

  摘要：

  The ligands [(BuSn)-Bu-n(2-pyridyl)(3)] and [RSn(methylthiomethyl)(3)] (R = Bu-n, Me) have been prepared in a one-pot, two-step procedure from the corresponding alkyltin trichloride and 2-pyridyl or methylthiomethyl carbanions. The reaction of these ligands with [M(CO)(3)(NCR)(3)] (M = Mo, W) afforded the tricarbonyl compounds [{(BuSn)-Bu-n(2-pyridyl)(3)}M(CO)(3)] and [{RSn(methylthiomethyl)(3)}M(CO)(3)]. In addition to IR and NMR characterization, the structure of three of these new complexes was determined by single-crystal X-ray diffraction.

  DOI：

  10.1021/om0104722