| 352655-27-7

• CAS: 352655-27-7
• 化学式: C₂₇H₃₇BCl₃N₂P₂ReS₂
• 分子量: 819.061
• InChiKey: ULKQYKPGVQFCIQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloronitridotris(dimethylphenylphosphine)rhenium(V) 、 钠二乙基氨基二硫代甲酸盐三水合物 、 二氯苯酚溴酯 以 二氯甲烷 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Zur Reaktion von Dichlorphenylboran mit Nitridokomplexen des Rheniums

  摘要：

  BCl2Ph reacts with terminal nitrido ligands of rhenium complexes under formation of a nitrogen bridge between the transition metal and boron. Structural studies on [Re(NBCl2Ph)Cl-2(Ph3P)(2)], [Re(NBCl2Ph)Cl-2(Me2PhP)(3)], [Re(NBCl2Ph)Cl(Me2PhP)(2)(Et(2)dtc)] and [Re(NBCl2Ph)-(Me2PhP)(Et(2)dtc)(2)] (Et(2)dtc(-) = N,N'-diethyldithiocarbamate) demonstrate that the rhenium-nitrogen bond is only slightly lengthened upon the formation of the nitrido bridge whereas a significant decrease of the structural trans influence of the nitrido ligand is observed.[Re(NBCl2Ph)Cl-4(Y)](-) (Y = Cl or solvent) complexes are formed during the reaction of [ReNCl4](-) with BCl2Ph. The rhenium(VI) compounds (d(1)configuration) can easily be detected by EPR spectroscopy. The formation of {Re(NBCl2Ph)} complexes with mixed Cl-/Br- (or NCS-) coordination spheres is evident when the reactions start from [ReNBr4](-) or [ReN(NCS)(5)](2-) which can be derived from the EPR spectra of the reaction mixtures.

  DOI：

  10.1002/1521-3749(200105)627:5<955::aid-zaac955>3.0.co;2-b