1-methyl-3-hexylimidazolium chlorogallate | 931113-89-2

• 英文名称: 1-methyl-3-hexylimidazolium chlorogallate
• CAS: 931113-89-2
• 化学式: C₁₀H₁₉N₂*Cl₄Ga
• 分子量: 378.809
• InChiKey: GXKVNVQTHUWSHL-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氯化镓 、 1-己基-3-甲基咪唑氯化物 以 neat (no solvent) 为溶剂， 生成 1-methyl-3-hexylimidazolium chlorogallate
  参考文献：
  名称：

  Estimation of Physicochemical Properties of Ionic Liquid C₆MIGaCl₄ Using Surface Tension and Density

  摘要：

  An ionic liquid (IL) C6MIGaCl4 (1-methyl-3-hexylimidazolium chlorogallate) was prepared by directly mixing GaCl3 and 1-methyl-3-hexylimidazolium chloride with molar ratio of 1/1 under dry argon. The density and surface tension of the IL were determined in the temperature range of 283.15-338.15 K. The ionic volume and surface entropy of the IL were estimated by extrapolation, respectively. In terms of Glasser's theory, the standard molar entropy and lattice energy of the IL were estimated, respectively. By use of Kabo's method, the molar enthalpy of vaporization of the IL, Delta H-g(l)m(0) (298 K), at 298 K was estimated. According to the interstice model, the thermal expansion coefficient of IL C6MIGaCl4, alpha, was calculated and in comparison with experimental value; their magnitude order is in good agreement.

  DOI：

  10.1021/jp068793k