[(HgBr2TeMes2)2HgBr2] | 1168152-83-7

• 英文名称: [(HgBr2TeMes2)2HgBr2]
• CAS: 1168152-83-7
• 化学式: C₃₆H₄₄Br₆Hg₃Te₂
• 分子量: 1813.14
• InChiKey: RLLFWIFNXHITEG-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dimesityl ditelluride 、 mercury dibromide 以 四氢呋喃 、 甲醇 为溶剂， 以29%的产率得到[(HgBr2TeMes2)2HgBr2]
  参考文献：
  名称：

  A novel complex of mercury with double η6–π-aryl interactions

  摘要：

  (MesTe)(2) reacts with HgBr2 to give [(HgBr(2)TeMes(2))2HgBr(2)], a polymeric one-dimensional assembly of (mu-Br)Hg and alternating mercury center dot center dot center dot eta(6)-pi-aryl interactions. This polymeric structure is based on [{HgBr2(TeMes(2))}(2)HgBr2] centrosymmetric units with three mercury atoms having two different coordination geometries. The central Hg-II ion is coordinated to four bromine atoms in the same plane and to two mesityl groups from TeMes(2) via eta(6)-pi-aryl interactions. Each TeMes(2) is bonded to one of the surrounding HgII ions through the tellurium atom. The central Hg-II ion is located in a crystallographic centre of inversion and sandwiched by its coordinating mesityl groups. The [{HgBr2(TeMes(2))}(2)HgBr2] units are linked by weak Hg center dot center dot center dot Br interactions in chains running along the c-axis. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.03.016