[(dppe)CpFe(CO)SC(O)-3,5-(NO2)2C6H3] | 674772-41-9

• 英文名称: [(dppe)CpFe(CO)SC(O)-3,5-(NO2)2C6H3]
• CAS: 674772-41-9
• 化学式: C₃₉H₃₂FeN₂O₆P₂S
• 分子量: 774.553
• InChiKey: FVMLIAFHTBAAEW-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  (η5-C5H5)Fe(CO)2(SC(O)-C6H3-3,5-(NO2)2) 、 1,2-双(二苯基膦)乙烷 以 四氢呋喃 为溶剂， 以65%的产率得到[(dppe)CpFe(CO)SC(O)-3,5-(NO2)2C6H3]
  参考文献：
  名称：

  Controlled synthesis of mono-substituted diphosphine iron thiocarboxylate complexes CpFe(CO)(Ph2P(CH2)nPPh2)SCOR [n=1 (dppm), n=2 (dppe)]. X-ray crystal structure of CpFe(CO)(dppm-S)SCO-3,5-(NO2)2C6H3

  摘要：

  Controlled photolytic CO-substitution reaction of the organoiron thiocarboxylate complexes CpFe(CO)(2)SCOR (R=CH3, 2-NO2C6H4, 4-NO2C6H4, 3,5-(NO2)(2)C6H3) with diphosphines (Ph2P(CH2)(n)PPh2) [n = 1 (dppm), n = 2 (dppe)] at 0 degreesC using 1:1 (metal:ligand) molar ratio afforded exclusively the monosubstituted complexes CpFe(CO)(Ph2P(CH2)nPPh2)SCOR. The complex CpFe(CO)(Ph2PCH2P = S(Ph)(2))SCO-3,5-(NO2)(2)C6H3 has been prepared and its X-ray structure was determined. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2003.08.005