(PdCl(2,9-dimethyl-1,10-phenanthroline)2)PF6 | 101019-69-6

• 英文名称: (PdCl(2,9-dimethyl-1,10-phenanthroline)2)PF6
• CAS: 101019-69-6
• 化学式: C₂₈H₂₄ClN₄Pd*F₆P
• 分子量: 703.363
• InChiKey: HNKXNNCDUILNDH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  六氟磷酸银 、 dichloro(cycloocta-1,5-diene)palladium (II) 、 新铜试剂 以 丙酮 为溶剂， 以84%的产率得到(PdCl(2,9-dimethyl-1,10-phenanthroline)2)PF6
  参考文献：
  名称：

  Mono cationic palladium(II): Synthesis, characterization and catalytic activity in Suzuki coupling

  摘要：

  Monocationic five and four-coordinate Pd-II complexes have been synthesized in a facile manner involving the reaction of (COD) PdCl2 with AgPF6 and a nitrogen or phosphorus ligand. Complexes synthesized via this route are five coordinate [PdCl(2,9-Me(2)Phen)(2)]PF6 2 and four coordinate [L3PdCl]PF6 (L = PPh3, 3; P(p-Tol)(3), 4; P(OEt)(3); 5). ESI-MS studies at varying cone-voltage indicated ligand dissociation depending upon ligand cone-angle. A halo-bridged complex [PdCl(mu-Cl){P(p-Tol)(3)}](2) 7 has been isolated from 4 in methanol. The cationic complexes have been screened as catalyst in Suzuki coupling involving aryl halide and phenylboronic acid. Complex 4 showed appreciable turnover. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.03.045