[Pd(4-pyridylbenzoate)(1,1'-bis(diphenylphosphino)ferrocene)]n(OTf)n | 1040733-24-1

• 英文名称: [Pd(4-pyridylbenzoate)(1,1'-bis(diphenylphosphino)ferrocene)]n(OTf)n
• 英文别名: [Pd(PyC6H4CO2)(dppf)]n(OTf)n
• CAS: 1040733-24-1
• 化学式: CF₃O₃S*C₁₂H₈NO₂*C₃₄H₂₈FeP₂*Pd
• 分子量: 1008.08
• InChiKey: PMSVXBCFUGOCLP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 氯仿 、 silver trifluoromethanesulfonate 、 4-吡啶-4-基苯甲酸 、 乙腈 以 二氯甲烷 、 乙腈 为溶剂， 生成 [Pd(4-pyridylbenzoate)(1,1'-bis(diphenylphosphino)ferrocene)]n(OTf)n 、 [PdCl(4-pyridylbenzoic acid)(1,1'-bis(diphenylphosphino)ferrocene)](trifluoromethanesulfonate)*0.5chloroform*0.5Et2O
  参考文献：
  名称：

  Oligo- and Polymeric Pd^II and Pt^II Using Pyridyl Carboxylate Spacers for Topology Control

  摘要：

  An array of Pd-II and Pt-II supramolecular assemblies have been constructed using pyridyl carboxylates as spacers and phosphines [(C5H4PPh2)(2)Fe (dppf) and PPh3)] as supporting ligands. Different molecular topologies such as squares, triangles, rectangles, and polymers can be controlled by the spatial and directional character of the spacer. A change of the denticity of the phosphine does not affect the topological outcome. Significant differences, however, are observed for the congeneric analogues, with Pd-II showing a more pronounced tendency toward coordination polymer formation and its attached carboxyl a higher affinity toward Ag+. The ability of these assemblies to capture cations, such as Na+ in [Pt3Na(3-NC5H4CO2)(3)(OTf)(3)(PPh3)(6)](+) through hydrogen bonding or Ag+ in [PdAg(2-NC5H4CO2)(OTf)(2)(dppf)] through dative bonding, is described and compared. All of the complexes are structurally characterized by single-crystal X-ray crystallography.

  DOI：

  10.1021/ic8007238