[Pb(η2-o-OOCC6H4Fc)(phen)](NO3) | 1123209-75-5

• 英文名称: [Pb(η2-o-OOCC6H4Fc)(phen)](NO3)
• 英文别名: [Pb(η2-o-ferrocenylbenzoate)(1,10-phenanthroline)]NO3
• CAS: 1123209-75-5
• 化学式: C₂₉H₂₁FeN₂O₂Pb*NO₃
• 分子量: 754.55
• InChiKey: MAQZANUVAISYNG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 lead(II) nitrate 、 sodium o-ferrocenylbenzoate 以 甲醇 、 水 为溶剂， 以72%的产率得到[Pb(η2-o-OOCC6H4Fc)(phen)](NO3)
  参考文献：
  名称：

  Syntheses and structures’ influence on the nonlinear optical properties of o-ferrocenylbenzoate compounds

  摘要：

  Two complexes containing o-ferrocenylbenzoate [ o- OOCH(4)C(6)Fc, Fc = (eta(5)-C5H5)Fe(eta(5)-C5H4)] components: {[Pb(eta(2)-o-OOCH(4)C(6)Fc)(2)(phen)](NO3)} (phen = phenanthroline) (1) and {[Zn(eta(2)-o-OOCH(4)C(6)Fc)(2)(bpe)](CH3OH)}(n) (bpe = 1,2-bis(4-pyridyl)ethene) (2) have been synthesized and structurally characterized by single crystal X-ray diffraction. 1 gives a discrete mononuclear framework, 2 features an in. finite 1-D chain structure constructed by the bpe linking two adjacent zinc (II) ions. The third-order nonlinear optical (NLO) properties of complexes 1, 2 and the reactant o-NaOOCH(4)C(6)Fc were determined by Z-scan techniques in DMF solution. The results show that the structures of complexes have great impact on NLO properties. Complex 1 and o-NaOOCH(4)C(6)Fc display self-defocusing behaviors, while complex 2 exhibits strong self-focusing effect. The solution-state differential pulse voltammograms of complexes 1, 2 and o-NaOOCH(4)C(6)Fc were investigated as well. The results reveal that the half-wave potential of the ferrocenyl moieties is strongly influenced by the Pb(II) or Zn(II) ions in complexes 1 and 2. (C) 2008 Published by Elsevier B.V.

  DOI：

  10.1016/j.ica.2008.04.010