bis(μ-acetato)-1:2κ(2)O:O';2:3κ(2)O;O'-bis[μ-2,2'-[1,3-propanediylbis(nitrilomethylidene)]diphenolato]-1κ(4)N,N',O,O':2κ(2)O,O';3κ(4)N,N',O,O':2κ(2)O,O'-tricadmium(II) | 235743-76-7

• 英文名称: bis(μ-acetato)-1:2κ(2)O:O';2:3κ(2)O;O'-bis[μ-2,2'-[1,3-propanediylbis(nitrilomethylidene)]diphenolato]-1κ(4)N,N',O,O':2κ(2)O,O';3κ(4)N,N',O,O':2κ(2)O,O'-tricadmium(II)
• CAS: 235743-76-7
• 化学式: C₃₈H₃₈Cd₃N₄O₈
• 分子量: 1015.97
• InChiKey: YMDATLORJFNZDO-FOWFEXJWSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-二亚水杨基-1,3-二氨基丙烷 、 cadmium(II) acetate 以 甲醇 为溶剂， 生成 bis(μ-acetato)-1:2κ(2)O:O';2:3κ(2)O;O'-bis[μ-2,2'-[1,3-propanediylbis(nitrilomethylidene)]diphenolato]-1κ(4)N,N',O,O':2κ(2)O,O';3κ(4)N,N',O,O':2κ(2)O,O'-tricadmium(II)
  参考文献：
  名称：

  A linear trinuclear Cd^II–Cd^II–Cd^IIcomplex with a μ-acetato bridge: bis{(μ-acetato)[μ-bis(salicylidene)-1,3-propanediaminato]cadmium(II)}cadmium(II)

  摘要：

  The title complex, bis(mu-acetato)-1:2 kappa(2)O:O';2:3 kappa(2)O:O'-bis{mu-2,2'-[1,3-propanediylbis(nitrilomethylidene)]di phenolato}-1 kappa(4)N,N',O,O':2 kappa(2)O,O';3 kappa(4)N,N',O,O':2 kappa(2)O,O'-tricadmium(II), [Cd{Cd(C17H16N2O2)(CH3CO2)}(2)], consists of a doubly oxygen-bridged linear homotrinuclear complex. The outer Cd-II ions, related by an inversion centre, have an irregular square-pyramidal coordination. The central Cd-II ion has an irregular octahedral coordination and lies on an inversion centre. The metal-metal bridging distance is 3.2582 (3) Angstrom.

  DOI：

  10.1107/s0108270199004333