| 1287673-80-6

• CAS: 1287673-80-6
• 化学式: C₈₁H₇₁ClN₄O₁₆Sn
• 分子量: 1510.63
• InChiKey: JAWMCXNYBUFMKL-VPGDKSHCSA-J

反应信息

• 作为产物：
  描述：

  5,10,15-tris(4-tert-butylphenyl)-2:3,7:8,12:13,17:18-tetrabenzo-2'',3'',7'',8'',12'',13'',17'',18''-octakis(carboxymethyl)corrole 在 tin(ll) chloride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 以51%的产率得到
  参考文献：
  名称：

  Synthetic Routes to 5,10,15-Triaryl-tetrabenzocorroles

  摘要：

  Two different synthetic routes for the preparation of 5,10,15-triaryl-tetrabenzocorroles have been developed. The first approach is based on the condensation of a tetrahydroisoindole with aryl-aldehydes, and the second pathway involves a cross-coupling reaction between a bromo-substituted corrole and a suitable substrate to form the four beta-fused aryl rings. These routes are successful to lead to the target tetrabenzocorroles, obtained in both cases as the corresponding Cu complex and with the highest yield obtained via the one-step cross-coupling methodology. Demetalation of the Cu-tetrabenzocorrole produces the corresponding free base; this macrocycle was further exploited to obtain the Sn and Co complexes in good yields.

  DOI：

  10.1021/jo200026u