[Mn(2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene)(μ1.5-N(CN)2)](PF6) | 616861-74-6

• 英文名称: [Mn(2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene)(μ1.5-N(CN)2)](PF6)
• CAS: 616861-74-6
• 化学式: C₁₇H₂₃MnN₈*F₆P
• 分子量: 539.325
• InChiKey: OUMUUMWRLHNOAK-YBRXSBAKSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium hexaflorophosphate 、 sodium dicyanamide 、 [(2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene)diaquamanganese(II)] dichloride tetrahydrate 以 水 为溶剂， 以85%的产率得到[Mn(2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene)(μ1.5-N(CN)2)](PF6)
  参考文献：
  名称：

  [Mn(MAC){μ1,5-N(CN)2}](PF6): a new one-dimensional coordination polymer with μ1,5-dicyanamido bridges (MAC=pentaaza macrocyclic ligand)—synthesis, crystal structure and magnetic properties

  摘要：

  The dicyanamido-bridged manganese(II) compound, [Mn(MAC){mu(1,5)-N(CN)(2)}](PF6), (1), has been obtained by reacting [Mn(MAC)(H2O)(2)]Cl-2.4H(2)O with NaN(CN)(2) and NaPF6 in a 1: 1: 1 molar ratio (MAC = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-[12.3.1]octadeca-1(18),2,12,14,16-pentaene). The structure consists of [Mn(MAC){mu(1,5)-N(CN)(2)}](n)(n+) infinite chains and uncoordinated PF6- ions. The manganese ions display a pentagonal-bipyramidal geometry, with the macrocyclic ligand forming the equatorial plane. The {Mn(MAC)} units are connected through mu(1,5)-dicyanamido bridges (both nitrile nitrogens coordinated). The cryomagnetic investigation of 1 reveals a very weak exchange interaction between the manganese(II) ions within the chain (J = -0.49 cm(-1)). (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00283-3