{((2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene)(bis(1H-indazol-1-yl)phenylmethyl)rhodium(I)}PF6 | 153295-01-3

• 英文名称: {((2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene)(bis(1H-indazol-1-yl)phenylmethyl)rhodium(I)}PF6
• CAS: 153295-01-3
• 化学式: C₂₈H₂₄N₄Rh*F₆P
• 分子量: 664.395
• InChiKey: MUWMVGPCOCSYKJ-UDCMMTCZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 [(norbornadiene)rhodium(I)chloride]2 、 1,1'-diindazolylphenylmethane 以 甲醇 为溶剂， 以83%的产率得到{((2,3,5,6-η)-bicyclo{2.2.1}hepta-2,5-diene)(bis(1H-indazol-1-yl)phenylmethyl)rhodium(I)}PF6
  参考文献：
  名称：

  （2,5-降冰片二烯）铑（I）与双和三（azol-1-yl）甲烷的配合物

  摘要：

  Reactions of bis[(2,3,5,6-eta)-bicyclo[2.2.1]hepta-2,5-diene]bis(mu-chloro)dirhodium, [RhCl-(NBD)]2, with bis- and tris(azolyl)methanes have been performed in methanol and acetone with 1:1 and 1:2 [RhCl(NBD)]2/ligand molar ratios. The structures of the complexes have been characterized by infrared and H-1 and C-13 NMR spectroscopy as well as X-ray diffraction analysis. Cationic species have been evidenced in the solid state while equilibria between cationic and neutral species have been established in solution.

  DOI：

  10.1021/om00013a042