| 420135-74-6

• CAS: 420135-74-6
• 化学式: C₁₀H₁₅ClN₃Pd*Cl
• 分子量: 354.575
• InChiKey: REIXEZIZBCPNIS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 silver trifluoromethanesulfonate 以 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Catalytic activity of palladium(II) complexes with tridentate nitrogen ligands in the hydrogenation of alkenes and alkynes

  摘要：

  A series of palladium(II) complexes with the nitrogen ligands N-pyridin-2-yl-N'-pyridin-2-ylmethylene-hydrazine (HL1), and N,N-dimethyl-N'-pyridin-2-ylmethylene-ethane-1,2-diamine, (L-2) have been synthesised and their catalytic activity in the hydrogenation of alkenes and alkynes in mild conditions (P-H2 = 1 atm, T = 40degreesC) has been studied. Ligand L-2 behaves as tridentate in the complexes Pd(L-2)Cl-2 (4) and [Pd(L-2)Cl](OTf) (5), whose catalytic activity is negligible in the hydrogenation of the tested substrates (styrene and phenylacetylene). The complexes Pd(L-1)Cl (1) and Pd(L-1)(OAc) (2) show a good catalytic activity towards styrene and phenylacetylene under homogeneous conditions. The high insolubility of the complex Pd-3(L-1)(2)Cl-4 (3) prevents its use as catalyst in homogeneous hydrogenations; however, it has been employed in heterogeneous conditions, showing a very good chemo- and stereo-selectivity in the semi-hydrogenation of alkynes (phenylacetylene, diphenylacetylene and 4-octyne). (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(01)00286-2
• 作为产物：
  描述：

  dichloro(cycloocta-1,5-diene)palladium (II) 、 2-((pyridin-2-ylmethylene)amino)ethanol 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Catalytic activity of palladium(II) complexes with tridentate nitrogen ligands in the hydrogenation of alkenes and alkynes

  摘要：

  A series of palladium(II) complexes with the nitrogen ligands N-pyridin-2-yl-N'-pyridin-2-ylmethylene-hydrazine (HL1), and N,N-dimethyl-N'-pyridin-2-ylmethylene-ethane-1,2-diamine, (L-2) have been synthesised and their catalytic activity in the hydrogenation of alkenes and alkynes in mild conditions (P-H2 = 1 atm, T = 40degreesC) has been studied. Ligand L-2 behaves as tridentate in the complexes Pd(L-2)Cl-2 (4) and [Pd(L-2)Cl](OTf) (5), whose catalytic activity is negligible in the hydrogenation of the tested substrates (styrene and phenylacetylene). The complexes Pd(L-1)Cl (1) and Pd(L-1)(OAc) (2) show a good catalytic activity towards styrene and phenylacetylene under homogeneous conditions. The high insolubility of the complex Pd-3(L-1)(2)Cl-4 (3) prevents its use as catalyst in homogeneous hydrogenations; however, it has been employed in heterogeneous conditions, showing a very good chemo- and stereo-selectivity in the semi-hydrogenation of alkynes (phenylacetylene, diphenylacetylene and 4-octyne). (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(01)00286-2