| 1114543-41-7

• CAS: 1114543-41-7
• 化学式: C₄₅H₄₈ClFeN₃
• 分子量: 722.196
• InChiKey: JKEOBEPEWHGSOA-DPKQYIRLSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-叠氮基-1,3,5-三甲基苯 、 (1,5,9-trimesityldipyrromethene)FeCl(THF) 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  C−H Bond Amination from a Ferrous Dipyrromethene Complex

  摘要：

  In this Communication, we report an intramolecular C-H bond amination reaction of a dipyrromethene ferrous complex with organic azides. Monitoring of the spectral changes (variable-temperature NMR and UV-vis) of the Fell complex reveals no buildup of an intermediate during conversion of the starting material into the nitrene-inserted product. The rate-determining step appears to be azide addition to the 14-electron FeII complex, hinting at the potential that these and related platforms may have to effect atom- and group-transfer processes.

  DOI：

  10.1021/ic900219b