(苯基异腈)金(I)氯化物 | 67623-10-3
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物化性质
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计算性质
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ADMET
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安全信息
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SDS
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制备方法与用途
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上下游信息
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文献信息
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表征谱图
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同类化合物
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相关功能分类
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相关结构分类
计算性质
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辛醇/水分配系数(LogP)：None
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重原子数：None
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可旋转键数：None
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环数：None
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sp3杂化的碳原子比例：None
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拓扑面积：None
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氢给体数：None
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氢受体数：None
反应信息
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作为反应物：描述：(苯基异腈)金(I)氯化物 以 neat (no solvent) 为溶剂， 生成 金参考文献：名称：Gold(
i )–isocyanide and gold(i )–carbene complexes as substrates for the laser decoration of gold onto ceramic surfaces摘要：我们制备了异氰酸金络合物 XAu(RNC)（X = 卤化物、假卤化物，R = 烷基、芳基）和水溶性羰基金络合物 XAuC(NHPh)[MeN(CH2CH2O)nMe] （X = Cl，n = 1â11），并对其进行了评估，将其作为在陶瓷上直接激光写金装饰的基底。DOI：10.1039/b617347k -
作为产物：描述：参考文献：名称：Neutral isocyanide and carbene pentafluorophenyl complexes of gold(I) and gold(III)摘要：DOI：10.1016/s0020-1693(00)87441-1
文献信息
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Structural Investigation of Bis(isonitrile)gold(I) Complexes作者：Wolfgang Schneider、Alexander Sladek、Andreas Bauer、Klaus Angermaier、Hubert SchmidbaurDOI：10.1515/znb-1997-0110日期：1997.1.1
The reaction of (MeNC)-, (PhNC)- and (MesNC)AuCl in tetrahydrofuran with an equimolar amount of the corresponding isonitrile ligand and one equivalent of Ag+X- (X-= BF- 4 or CF3SO- 3) leads to the formation of the bis(isonitrile)gold(I) complexes (MeNC)2Au+ CF3SO- 3(1), (PhNC)2Au+ BF- 4 (2) and (MesNC)2Au+ BF- 4(3). The crystal structures of 1, 2 and 3 have been determined. In compound 1 there are rod-like cations with a parallel packing into meandering puckered layers, in which the gold atoms have alternating Au-Au contacts of 3.611 and 3.624 Å. In complex 2 the cations form long double-paddles, with the two paddles at an angle of 77.5°. The individual cations are well separated and have no sub-van-der-Waals Au-Au contacts. The crystal structure of 3 is similar, but with a smaller dihedral angle between the planes of the two mesityl rings (56.0°)
(MeNC)-、(PhNC)-和(MesNC)AuCl在四氢呋喃中与相应的异腈配体的等摩尔量和一当量的Ag^+X^- (X^-= BF^-4或CF3SO3-) 反应，形成双(异腈)金(I)配合物(MeNC)2Au^+ CF3SO3-3(1)、(PhNC)2Au^+ BF^-4(2)和(MesNC)2Au^+ BF^-4(3)。已确定了1、2和3的晶体结构。在化合物1中，有棒状阳离子平行堆积成蜿蜒起伏的层，金原子之间交替的Au-Au接触为3.611和3.624 Å。在复合物2中，阳离子形成长双桨，两个桨之间的夹角为77.5°。单个阳离子之间相互分离，没有亚-范德瓦尔斯Au-Au接触。化合物3的晶体结构类似，但两个二甲苯环的平面之间的二面角较小(56.0°)。 -
A Screening Approach for the Discovery of Mechanochromic Gold(I) Isocyanide Complexes with Crystal-to-Crystal Phase Transitions作者：Tomohiro Seki、Yuki Takamatsu、Hajime ItoDOI：10.1021/jacs.6b02409日期：2016.5.18Mechanoinduced phase transitions of emissive organic crystalline materials have received much attention. Although a variety of such luminescent mechanochromic compounds have been reported, it is challenging to develop mechanochromic compounds with crystal-to-crystal phase transitions in which precise structural information about molecular arrangements can be obtained. Here, we report a screening approach发光有机晶体材料的机械诱导相变受到了广泛关注。尽管已经报道了各种此类发光机械变色化合物，但开发具有晶体到晶体相变的机械变色化合物具有挑战性，其中可以获得有关分子排列的精确结构信息。在这里，我们报告了一种筛选方法来探索表现出晶体到晶体相变的机械变色化合物。我们制备了 48 个对位取代的 (R(1)) 苯基[对位取代的 (R(2)) 苯基异氰化物] 金 (I) 配合物，指定为 R(1)-R(2)（六个 R(1) 和八个 R （2）取代基），然后进行三步筛选实验。第一个筛选步骤是在紫外光下选择发射复合物，得到 37 个发射 R(1)-R(2) 复合物。第二个筛选步骤涉及通过发射光谱评估机械变色特性。发现 28 种复合物是机械变色的。第三个筛选步骤涉及制备 28 种机械变色 R(1)-R(2) 配合物的单晶、再沉淀粉末和研磨粉末。研究了由机械刺激引起的这些配合物的粉末衍射图案的变化。两种化合物在机
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Ligand Influences on the Supramolecular Chemistry of Simple Gold(I) Complexes: Mononuclear (Isonitrile)gold(I) Complexes作者：Wolfgang Schneider、Klaus Angermaier、Alexander Sladek、Hubert SchmidbaurDOI：10.1515/znb-1996-0606日期：1996.6.1
Abstract A series of (isonitrile)gold(I) complexes has been synthesized: (MeNC)AuX (X = Cl la, I lc), (t-BuNC)AuBr 2b. (PhNC)AuX (X = Cl 3a. Br 3b. I 3c. SCN 3d), (MesNC)AuCl 4a [mes=mesityl], and (MeOC(O)CH2NC)AuX (X = Cl 5a. Br 5b. I 5c. SCN 5d). The chlorides were prepared by the reaction of (Me2S)AuCl with equimolar amounts (or with an excess) of the corresponding isonitrile. The bromides, iodides and thiocyanates were obtained from the reaction of (RNC)AuCl with K+X- (X = Br, I, SCN) in the two-phase system H2O/CH2CI2. The molecular and crystal structures of la. 2b. 3a-c, 4a, and 5a-c have been determined by X-ray diffraction methods. In the solid state the molecules are aggregated through short Au-Au contacts into dimers (4a and 5c), chains (la, 2b and 3a-c) or sheets (5a and 5b). The influence of the isonitrile and halide ligands on the type and strength of the intermolecular Au-A u contacts is discussed
摘要 合成了一系列（异腈）金（I）配合物：（MeNC）AuX（X = Cl la，I lc），（t-BuNC）AuBr 2b，（PhNC）AuX（X = Cl 3a，Br 3b，I 3c，SCN 3d），（MesNC）AuCl 4a [mes = 甲基丙烯酸甲酯基] 和（MeOC（O）CH2NC）AuX（X = Cl 5a，Br 5b，I 5c，SCN 5d）。氯化物是通过（Me2S）AuCl与相应的异腈的等摩尔量（或过量）反应制备的。溴化物、碘化物和硫氰酸盐是从（RNC）AuCl与K+X-（X = Br，I，SCN）在两相系统H2O / CH2CI2中反应得到的。la，2b，3a-c，4a和5a-c的分子和晶体结构已通过X射线衍射法确定。在固态中，分子通过短的Au-Au接触聚集成二聚体（4a和5c），链（la，2b和3a-c）或片（5a和5b）。讨论了异腈和卤化物配体对分子间Au-Au接触类型和强度的影响。
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Organogold(I)-uracil conjugates: Synthesis and structural characterization作者：Yuki Sakamoto、Toshiyuki Moriuchi、Toshikazu HiraoDOI：10.1016/j.jorganchem.2014.10.035日期：2015.4The conjugation of the gold(I) complex having planar phenyl isocyanide or bulky triphenylphosphine with 6-ethynyl-1-octyluracil afforded the corresponding gold(I) complexes U6AuCNPh and U6AuPPh3, respectively, as bioorganometallic conjugates. The crystal structure of U6AuCNPh revealed the formation of a head-to-tail dimer through the Au(I)–Au(I) and π–π interactions between the uracil and benzene moieties具有平面苯基异氰化物或庞大的三苯基膦的金（I）配合物与6-乙炔基-1-辛基尿嘧啶的缀合分别提供了相应的金（I）配合物U6AuCNPh和U6AuPPh 3，作为生物有机金属共轭物。U6AuCNPh的晶体结构揭示了通过Au（I）–Au（I）和苯异氰酸酯的尿嘧啶和苯部分之间的π–π相互作用形成了从头到尾的二聚体。此外，每个头到尾的二聚体不仅通过尿嘧啶部分之间的N–H···O型分子间氢键连接，而且还通过尿嘧啶和苯之间的CH–···O型弱氢键连接。苯基异氰基的部分。相反，在U6AuPPh 3的晶体结构中未观察到Au（I）-Au（I）相互作用，这可能是由于庞大的三苯基膦配体的空间位阻，尽管通过NH- ······································································ ·尿嘧啶部分之间形成O型。
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Photoinduced single-crystal-to-single-crystal phase transition and photosalient effect of a gold(<scp>i</scp>) isocyanide complex with shortening of intermolecular aurophilic bonds作者：Tomohiro Seki、Kenta Sakurada、Mai Muromoto、Hajime ItoDOI：10.1039/c4sc02676d日期：——
We report the first photoinduced single-crystal-to-single-crystal phase transition of a gold complex that involves shortening of intermolecular aurophilic bonds. The gold(
i ) isocyanide complex also shows a photosalient effect.
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