[n-Bu4N][Mo6Br13(4-tert-butylpyridine)] | 876861-31-3

• 英文名称: [n-Bu4N][Mo6Br13(4-tert-butylpyridine)]
• CAS: 876861-31-3
• 化学式: C₉H₁₃Br₁₃Mo₆N*C₁₆H₃₆N
• 分子量: 1992.07
• InChiKey: KDELZNNLFIVIOP-UHFFFAOYSA-A

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-叔丁基吡啶 、 [n-Bu4N]2[Mo6Br13(CF3SO3)] 以 四氢呋喃 为溶剂， 以48%的产率得到[n-Bu4N][Mo6Br13(4-tert-butylpyridine)]
  参考文献：
  名称：

  From Simple Monopyridine Clusters [Mo₆Br₁₃(Py-R)][n-Bu₄N] and Hexapyridine Clusters [Mo₆X₈(Py-R)₆][OSO₂CF₃]₄ (X = Br or I) to Cluster-Cored Organometallic Stars, Dendrons, and Dendrimers

  摘要：

  Hexasubstitution of apical triflate ligands in the octahedral clusters [M](2)[Mo6X8(CF3SO3)(6)] (M = n-BU4N or Cs, X = Br or 1) and monosubstitution in [n-Bu4N](2)[Mo6Br13(CF3SO3)] was carried out in tetrahydrofuran at 60 degrees C with simple pyridines and then extended to organometallic pyridines, yielding cluster-cored stars, and to dendronic polyallyl and polyferrocenylpyridines, yielding cluster-cored polyallyl and polyferrocenyl dendrimers and dendrons. The orange pyridine-substituted clusters, whose pyridine protons are deshielded in H-1 NMR (a practical tool for characterization), are air-stable and thermally stable with simple pyridines, light- and air-sensitive with organometallic pyridines, and air-fragile and thermally fragile with large dendronized pyridines.

  DOI：

  10.1021/ic051680f