| 545411-32-3

• CAS: 545411-32-3
• 化学式: C₃₉H₂₇BF₁₅PZr
• 分子量: 913.628
• InChiKey: TXZMUUPXACFWQE-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  cyclopenta-1,3-diene;tris(2,3,4,5,6-pentafluorophenyl)-(2-phenylethyl)boranuide;zirconium(4+) 、 三甲基膦 以 further solvent(s) 为溶剂， 以96%的产率得到
  参考文献：
  名称：

  Investigations on 1‐Metallaindanes

  摘要：

  Abstract1‐Mercuraindane (6) was prepared in three steps from 1‐bromo‐2‐(2‐bromoethyl)benzene (3) and converted into 1‐magnesaindane (1) by reaction with magnesium. In solution,6was observed to occur in a remarkable dimer/trimer equilibrium, whereas1forms a dimer. From1and dichlorozirconocene, the 1‐zirconaindane2was obtained, which reacted with B(C6F5)3to form the adduct13. According to spectroscopic data,13is formed by attack of the β‐methylene carbon atom at the boron atom and has a zwitterionic structure with weak interactions between the zirconium ion and one of theortho‐fluorine atoms. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

  DOI：

  10.1002/ejic.200390088