[Mn(CO)4(1,2-bis(diphenylphosphino)ethane)]Cl | 201486-95-5

• 英文名称: [Mn(CO)4(1,2-bis(diphenylphosphino)ethane)]Cl
• CAS: 201486-95-5；52901-73-2
• 化学式: C₃₀H₂₄MnO₄P₂*Cl
• 分子量: 600.857
• InChiKey: HSOSUYSOWZPCLM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Mn(CO)4(1,2-bis(diphenylphosphino)ethane)]Cl 以 neat (no solvent) 为溶剂， 生成 fac-Mn(CO)3(chloro)(1,2-bis(diphenylphosphino)ethane)
  参考文献：
  名称：

  Conversion of a manganese-carbon-bonded complex to a manganese-oxygen-bonded complex, some reactions of manganese carbonato complexes

  摘要：

  Stirring a solution of the manganese carboxylate, (dppe)(CO)(3)Mn-C(O)OCH3, 1, in dichloromethane saturated with water converts it to the bridging carbonato complex, (dppe)(CO)(3)Mn-OC(O)O-Mn(CO)(3)(dppe), 2. This multi-step con vers ion involves the in-situ transformation of a Mn-C bonded complex to a Mn-O bonded one. When 2 is stirred with HCl, it is converted quantitatively to the covalent chloride (dppe)(CO)(3)Mn-Cl, 11, with evolution of carbon dioxide. Similar HCl treatment of the manganese carboxylate 1 gives three compounds: the same covalent chloride, 11; the ionic chloride, [(dppe)(CO)(4)Mn]Cl-+(-), 12, and the hydride, (dppe)(CO)(3)Mn-H, 5. Reasonable schemes for these conversions are suggested. Heating the ionic chloride complex to its melting point converts it to the covalent chloride complex; the same transformation is accomplished by refluxing the ionic chloride in acetonitrile. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00486-5
• 作为产物：
  描述：

  盐酸 、 [Mn(CO)4(1,2-bis(diphenylphosphino)ethane)](BF4) 以 二氯甲烷 为溶剂， 生成 [Mn(CO)4(1,2-bis(diphenylphosphino)ethane)]Cl
  参考文献：
  名称：

  Conversion of a manganese-carbon-bonded complex to a manganese-oxygen-bonded complex, some reactions of manganese carbonato complexes

  摘要：

  Stirring a solution of the manganese carboxylate, (dppe)(CO)(3)Mn-C(O)OCH3, 1, in dichloromethane saturated with water converts it to the bridging carbonato complex, (dppe)(CO)(3)Mn-OC(O)O-Mn(CO)(3)(dppe), 2. This multi-step con vers ion involves the in-situ transformation of a Mn-C bonded complex to a Mn-O bonded one. When 2 is stirred with HCl, it is converted quantitatively to the covalent chloride (dppe)(CO)(3)Mn-Cl, 11, with evolution of carbon dioxide. Similar HCl treatment of the manganese carboxylate 1 gives three compounds: the same covalent chloride, 11; the ionic chloride, [(dppe)(CO)(4)Mn]Cl-+(-), 12, and the hydride, (dppe)(CO)(3)Mn-H, 5. Reasonable schemes for these conversions are suggested. Heating the ionic chloride complex to its melting point converts it to the covalent chloride complex; the same transformation is accomplished by refluxing the ionic chloride in acetonitrile. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00486-5