[Mo(η3-methallyl)(tert-butyl isocyanide)(4,4'-bis((4-methylphenyl)carbamoyl)-2,2'-bipyridine)(CO)2][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate] | 934187-30-1

• 英文名称: [Mo(η3-methallyl)(tert-butyl isocyanide)(4,4'-bis((4-methylphenyl)carbamoyl)-2,2'-bipyridine)(CO)2][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate]
• CAS: 934187-30-1
• 化学式: C₃₂H₁₂BF₂₄*C₃₇H₃₈MoN₅O₄
• 分子量: 1575.9
• InChiKey: GBKJJQWPISLFBH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Mo(η3-methallyl)(tert-butyl isocyanide)(4,4'-bis((4-methylphenyl)carbamoyl)-2,2'-bipyridine)(CO)2][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate] 、 四丁基硫酸氢铵 以 not given 为溶剂， 生成 [Mo(η3-methallyl)(tert-butyl isocyanide)(4,4'-bis((4-methylphenyl)carbamoyl)-2,2'-bipyridine)(CO)2][HSO4]
  参考文献：
  名称：

  Biimidazole and Bis(amide)bipyridine Molybdenum Carbonyl Complexes as Anions Receptors

  摘要：

  Compounds [Mo(CO)(4)(N-N)] (N-N = 4,4'-bis((4-methylphenyl)carbamoyl)-2,2'-bipyridine, bipy', 1; or 2,2'-biimidazole, H(2)biim, 2), [MoCl(eta(3)-methallyl)(CO)(2)(N-N)] (N-N = bipy', 3; H(2)biim, 4), and [Mo(eta(3)-methallyl)((CNBu)-Bu-t)(CO2)(N-N)]BAr'(4) (Ar' = 3,5-bis(trifluoromethyl)phenyl; N-N= bipy', 5; H(2)biim, 6) were synthesized and characterized, and their behavior toward anions was investigated in solution (IR and H-1 NMR) and in solid state (X-ray diffraction).

  DOI：

  10.1021/ic0621650
• 作为产物：
  描述：

  [Mo(η3-methallyl)Cl(CO)2(acetonitrile)2] 、 4,4'-bis((4-methylphenyl)carbamoyl)-2,2'-bipyridine 、 异氰酸叔丁酯 、 四(3,5-二(三氟甲基)苯基)硼酸钠 以 二氯甲烷 、 乙腈 为溶剂， 以76%的产率得到[Mo(η3-methallyl)(tert-butyl isocyanide)(4,4'-bis((4-methylphenyl)carbamoyl)-2,2'-bipyridine)(CO)2][tetrakis(3,5-bis(trifluoromethyl)phenyl)borate]
  参考文献：
  名称：

  Biimidazole and Bis(amide)bipyridine Molybdenum Carbonyl Complexes as Anions Receptors

  摘要：

  Compounds [Mo(CO)(4)(N-N)] (N-N = 4,4'-bis((4-methylphenyl)carbamoyl)-2,2'-bipyridine, bipy', 1; or 2,2'-biimidazole, H(2)biim, 2), [MoCl(eta(3)-methallyl)(CO)(2)(N-N)] (N-N = bipy', 3; H(2)biim, 4), and [Mo(eta(3)-methallyl)((CNBu)-Bu-t)(CO2)(N-N)]BAr'(4) (Ar' = 3,5-bis(trifluoromethyl)phenyl; N-N= bipy', 5; H(2)biim, 6) were synthesized and characterized, and their behavior toward anions was investigated in solution (IR and H-1 NMR) and in solid state (X-ray diffraction).

  DOI：

  10.1021/ic0621650