spiro-N3P3(O2C12H8)(OC5H4N-2)4ZnCl2 | 1007872-45-8

• 英文名称: spiro-N3P3(O2C12H8)(OC5H4N-2)4ZnCl2
• CAS: 1007872-45-8
• 化学式: C₃₂H₂₄Cl₂N₇O₆P₃Zn
• 分子量: 831.803
• InChiKey: LKVFNPLHTGBXAX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (2,2'-dioxybiphenyl)tetrakis(2-pyridyloxy)cyclotriphosphazene 、 zinc(II) chloride 以 二氯甲烷 为溶剂， 以73.2%的产率得到spiro-N3P3(O2C12H8)(OC5H4N-2)4ZnCl2
  参考文献：
  名称：

  Synthesis, structure and metallation of spiro-N3P3(O2C12H8)(OC5H4N-2)4: A heptacoordinate Co(II) in the molecular structure of N3P3(O2C12H8)(OC5H4N-2)4·Co(NO3)2

  摘要：

  Spiro-N3P3(O2C12H8)(OC5H4N-2)(4) (L) is an efficient multi-site coordination ligand which binds with transition metal ions to afford the mononuclear complexes [LCu(NO3)(2)], [LCo(NO3)(2)] and [LZnCl2], In [LCu(NO3)(2)] the copper atom is six-coordinate with the cyclophosphazene ligand coordinating to the metal ion through one skeletal ring nitrogen atom and two nitrogen atoms of geminal pyridyloxy substituents in a eta(3)-gem-N-3 mode. The two nitrate ligands provide monodentate as well as chelating coordination. In [LCo(NO3)(2)] the coordination geometry around Co(II) is pentagonal bipyramidal with a 3N, 40 coordination environment. The cyclophosphazene ligand binds to the metal ion in a eta(3)-non-gem-N-3 mode. The two nitrate ligands function as chelating ligands and complete the coordination around cobalt. The coordination response of L in the complex [LZnCl2] is also eta(3)-non-gem-N-3. Two chloride ligands complete the coordination environment around zinc. (C) 2007 Published by Elsevier Ltd.

  DOI：

  10.1016/j.poly.2007.09.026