1-formyl-1'-[2-(4-methoxyphenyl)ethenyl]ferrocene | 911069-11-9

• 英文名称: 1-formyl-1'-[2-(4-methoxyphenyl)ethenyl]ferrocene
• CAS: 911069-11-9；482611-92-7
• 化学式: C₂₀H₁₈FeO₂
• 分子量: 346.209
• InChiKey: FTQJUZFTUCAFCM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  1-formyl-1'-[2-(4-methoxyphenyl)ethenyl]ferrocene 、 L-酪氨酸甲酯 以 二氯甲烷 为溶剂， 以76%的产率得到N-(1'-[(Z)-2-(4-methoxyphenyl)ethenyl]-1-ferrocenemethyl)-L-tyrosine methyl ester
  参考文献：
  名称：

  Synthesis, structural characterization and electrochemical study of 1,1′-ferrocenylene labeled amino acids

  摘要：

  Unsymmetrical 1,1'-disubstituted ferrocenes bearing an amino acid moiety and a conjugated electron density controlling substituent were synthesized conveniently starting from 1,1'-ferrocenedicarbaldehyde. The novel ferrocene amino acid derivatives were completely characterized from their MS, H-1 NMR and C-13 NMR spectra. Their electrochemical behavior was studied by cyclic voltammetry. Their formal redox potentials E-f were slightly influenced by the nature of the amino acid and mainly by the kind of the ethenyl substituent. Furthermore all the (Z)-isomers exhibited a slight anodic shift compared with the corresponding (E)-isomers. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.05.045