FeCl2(2-(di-tert-butylphosphinomethyl)-6-diethylaminomethyl)pyridine) | 886060-04-4

• 英文名称: FeCl2(2-(di-tert-butylphosphinomethyl)-6-diethylaminomethyl)pyridine)
• CAS: 886060-04-4
• 化学式: C₁₉H₃₅Cl₂FeN₂P
• 分子量: 449.227
• InChiKey: PXPRBPBTKBVBGY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 thallium(I) hexafluorophosphate 、 FeCl2(2-(di-tert-butylphosphinomethyl)-6-diethylaminomethyl)pyridine) 以 四氢呋喃 为溶剂， 以95%的产率得到FeCl(THF)(2-(di-tert-butylphosphinomethyl)-6-diethylaminomethyl)pyridine)PF6
  参考文献：
  名称：

  Iron(II) complexes based on electron-rich, bulky PNN- and PNP-type ligands

  摘要：

  Reaction of the PNN ligand ((2-(di-tert-butylphosphinomethyl)-6-diethylaminomethyl)pyridine) with I equiv. of anhydrous FeCl2 in THF results in the formation of (PNN)FeCl2 (1). The cationic complex [(PNN)Fe(THF)Cl](PF6) (2) was obtained by chloride abstraction from I with I equiv. of TlPF6. Similarly, the PNP-type complexes 3 and 4 were obtained from FeCl2 with I equiv. of t-Bu-PNP (2,6-bis(di-tert-butylphosphinomethyl)pyridine) and i-Pr-PNP (2,6-bis(di-iso-propylphosphinomethyl)pyridine), respectively. Complexes 1 and 3 were characterized by X-ray diffraction and elemental analyses. In both structures the Fe(II) centers exhibit a distorted square pyramidal geometry comprising two chloride ligands and one tridentate PNN or PNP ligand. The magnetic properties of the paramagnetic complexes 1-4 are discussed. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.11.039
• 作为产物：
  描述：

  2-(二叔丁基膦甲基-6-二乙氨基甲基)吡啶 、 iron(II) chloride 以 四氢呋喃 为溶剂， 以86%的产率得到FeCl2(2-(di-tert-butylphosphinomethyl)-6-diethylaminomethyl)pyridine)
  参考文献：
  名称：

  Iron(II) complexes based on electron-rich, bulky PNN- and PNP-type ligands

  摘要：

  Reaction of the PNN ligand ((2-(di-tert-butylphosphinomethyl)-6-diethylaminomethyl)pyridine) with I equiv. of anhydrous FeCl2 in THF results in the formation of (PNN)FeCl2 (1). The cationic complex [(PNN)Fe(THF)Cl](PF6) (2) was obtained by chloride abstraction from I with I equiv. of TlPF6. Similarly, the PNP-type complexes 3 and 4 were obtained from FeCl2 with I equiv. of t-Bu-PNP (2,6-bis(di-tert-butylphosphinomethyl)pyridine) and i-Pr-PNP (2,6-bis(di-iso-propylphosphinomethyl)pyridine), respectively. Complexes 1 and 3 were characterized by X-ray diffraction and elemental analyses. In both structures the Fe(II) centers exhibit a distorted square pyramidal geometry comprising two chloride ligands and one tridentate PNN or PNP ligand. The magnetic properties of the paramagnetic complexes 1-4 are discussed. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.11.039